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Stereoselective Partial Synthesis of (+)-Pisiferic Acid (1995)

Geiwiz, Jürgen ; Haslinger, Ernst

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 78 (1995), S. 818-832

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: (+)-Pisiferic acid (1), an antibiotic active against Gram-negative and Gram-positive bacteria, was synthesized starting from dehydroabietic acid (2) or abietic acid (26). The terpene ring system was functionalized and a Barton reaction used to oxidize Me(20). The intermediates of this photochemical reaction were isolated and characterized.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19950780404

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