ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The 1,2-carbenic hydride shift of neopentylmethoxycarbene was suppressed by the methoxy substituent. Thermally activated hydride shifts were observed with phenoxymethylmethoxycarbene and phenoxymethyltrifluoro-ethoxycarbene, where appropriate potentiating substituents were introduced at both the migration origin and the migration terminus. Similarly, the 1,3-CH insertion reaction of tert-butylfluorocarbene could be induced by thermal activation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610060611
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