ALBERT

Description: This data publication is supplementary to a study on the climatic controls on leaf wax hydrogen isotopes, by Gaviria-Lugo et al. (submitted). The dataset contains hydrogen isotope ratios from leaf wax n-alkanes (δ2Hwax) taken from soils, river sediments and marine surface sediments along a climatic gradient from hyperarid to humid in Chile. In addition, for each sampling site the hydrogen isotope ratios from precipitation (δ2Hpre) from the grids produced by the Online Isotopes in Precipitation Calculator (OIPC) (Bowen and Revenaugh, 2003). Furthermore, for each sampling site we report mean annual data of precipitation, actual evapotranspiration, relative humidity, and soil moisture, all derived from TerraClimate (Abatzoglou et al., 2018). Also provide data of mean annual temperature and the annual average of maximum daily temperature derived from WorldClim (Fick and Hijmans, 2017). As a final climatic parameter, we also derived data of aridity index from the Consultative Group of the International Agricultural Research Consortium for Spatial Information (CGIARCSI) (Trabucco and Zomer, 2022). In addition to climatic variables, for each site we include land cover fractions of trees, shrubs, grasses, crops, and barren land. These land cover fractions were obtained from Collection 2 of the Copernicus Global Land Cover layers (Buchhorn et al., 2020) via Google Earth Engine. For further comparison here we provide δ2Hwax compiled from 26 publications (see references) that reported both the n-C29 and n-C31 n-alkanes homologues from soils and lake sediments. For each sampling site of the global compilation, we provide δ2Hpre and the same climatic and land cover parameters as for the Chilean data (i.e., precipitation, actual evapotranspiration, relative humidity, soil moisture, aridity index, temperature, fraction of trees, fraction of grasses, etc.), using the same sources. The data is provided here as one single .xlsx file containing 9 data sheets, but also as 9 individual .csv files, to be accessed using the file format of preference. Additionally, 5 supplementary figures that accompany the publication Gaviria-Lugo et al. (submitted) are provided in one single .pdf file. The samples taken for this study were assigned International Geo Sample Numbers (IGSNs), which are included in the provided tables S4, S5 and S6.

Description: The hydrogen isotope composition of leaf wax biomarkers (δ2Hwax) is a valuable tool for reconstructing continental paleohydrology, since it serves as a proxy for the hydrogen isotope composition of precipitation (δ2Hpre). To yield robust palaeohydrological reconstructions using δ2Hwax in marine archives, it is necessary to examine the impacts of regional climate on δ2Hwax and assess the similarity between marine sedimentary δ2Hwax and the source of continental δ2Hwax. Here, we examined an aridity gradient from hyperarid to humid along the Chilean coast. We sampled sediments at the outlets of rivers draining into the Pacific as well as soils within catchments and marine surface sediments adjacent to the outlets of the studied rivers and analyzed the relationship between climatic variables and δ2Hwax values. We found that apparent fractionation between leaf waxes and source water is relatively constant in humid and semiarid regions (average: −121 ‰). However, it becomes less negative in hyperarid regions (average: −86 ‰) as a result of evapotranspirative processes affecting soil and leaf water 2H enrichment. We also observed that along strong aridity gradients, the 2H enrichment of δ2Hwax follows a nonlinear relationship with water content and water flux variables, driven by strong soil evaporation and plant transpiration. Furthermore, our results indicate that δ2Hwax values in marine surface sediments largely reflect δ2Hwax values from the continent, confirming the robustness of marine δ2Hwax records for paleohydrological reconstructions along the Chilean margin. These findings also highlight the importance of considering the effects of hyperaridity in the interpretation of δ2Hwax values and pave the way for more quantitative paleohydrological reconstructions using δ2Hwax.