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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 88 (2000), S. 6993-6996 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on crystallization and second- and third-order optical nonlinearities of GeO2–SiO2 glass poled with ArF laser irradiation. With laser power and 100 mJ/cm2/pulse, the treatment generates crystallites in the glass, provided that the poling field strength is greater than 0.5×105 V/cm. Its crystal structure is possibly the cristobalite phase of the Ge–Si–O system. A large coefficient of second-harmonic generation (SHG), d33, is induced in the glass with the crystallite generation, and its value is comparable to d22 of LiNbO3. Moreover, the third-order optical susceptibility χ(3) increases by a factor of approximately 15 compared to that of glass without the crystallites. Even after the d33 coefficient decays out, the crystallites and χ(3) are retained. The result suggests that the large SHG in the glass is not induced from inert second-order nonlinearity of the crystallites, but the main origin of the induction is the associated effective second-order nonlinearity with the formation of the space-charge field. © 2000 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 1481-1483 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report quantitative measurements on the decay of optical absorption at various elevated temperatures in ultraviolet (UV)-irradiated SiO2 glasses doped with Ge. From the Arrhenius plots of decay time constants, the activation energy of the Ge E′ center in the UV-irradiated glasses has been determined to be 2.4±0.3 eV, while the reported activation energy of Ge E′ decay in UV-poled glasses is 0.4±0.1 eV. The present experimental results strongly suggest that the decay process of the Ge E′ center induced in UV-irradiated glasses is quite different from that in UV-poled glasses. © 1998 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 72 (1998), S. 1287-1289 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In a 15.7 GeO2⋅84.3 SiO2 glass prepared by a vapor axial deposition method, optical absorptions at 4.92 and 5.08 eV were observed from 300 to 600 K. The results were then compared with electron spin resonance (ESR) measurement using the same samples. The absorption at 4.92 eV was found to increase with increasing temperature, while the optical absorption at 5.08 eV decreased with increasing temperature. These changes of optical absorption indicate that the concentration of neutral oxygen monovacancy is reduced at higher temperatures. The changes were quite reversible with the temperature. Concentration of Ge E′ center, estimated from ESR, increased with increasing temperature, which is in contrast with the decrease of neutral oxygen monovacancy. The present result strongly suggests the thermal equilibrium reaction between neutral oxygen monovacancy and Ge E′ center. © 1998 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 2718-2720 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report a remarkably reduced photorefractive sensitivity in Ti:LiNbO3 channel waveguides using substrates with reduced optical absorption near the absorption edge. In addition, the intensity dependence of the saturated index change was measured, which indicates that, based on the Glass model, the saturated value of photoinduced index change is independent of irradiation intensity in the high intensity limit.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 743-745 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We compare the photorefractive effect in proton-exchanged (PE) and annealed proton-exchanged (APE) LiNbO3 optical waveguides at the irradiation wavelength of 488 nm. We measure the intensity dependence of the saturated index change, the build-up time constant, and the photorefractive sensitivity in PE and APE waveguides. In APE waveguides the photorefractive sensitivity is about three times that of PE waveguides up to an irradiation intensity of 100 W/cm2. The contribution of the dark conductivity to the photorefractive effect in PE and APE waveguides is found to be dominant in the intensity range used in our experiments.
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 71 (1997), S. 1032-1034 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on a remarkably large second-harmonic generation (SHG) in a germanosilicate glass (15.7 GeO2–84.3 SiO2 in mol %), which was induced by poling while the sample was irradiated with the ArF laser at the wavelength of 193 nm. The SHG coefficient, d, thus induced was measured at various poling electric-field strengths using the Maker-fringe technique. The value of d increases with increasing poling field and then saturates around 1.5×105 V/cm. The largest d coefficient value obtained in this work, which is 3.4±0.3 pm/V, seems to exceed d22 of LiNbO3. Furthermore, polarization dependence of the induced SHG shows an anisotropy of the refractive index. © 1997 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 81 (2002), S. 223-225 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Optical second-order nonlinearity of ferroelastic Ba2TiGe2O8 crystal in transparent crystallized glasses was estimated by means of the Maker fringe technique. Transparent crystallized glasses were fabricated by crystallization of a glass with the composition of 30 BaO.15 TiO2.55 GeO2. The crystalline layer consisting of highly oriented Ba2TiGe2O8 crystals was formed at the surface of about 9 μm thickness, and a clear second-harmonic generation was observed. The optical second-order nonlinearity of d33 for Ba2TiGe2O8 crystal was found to be ∼10 pm/V, being comparable to d22 and d31 of LiNbO3, and demonstrating that Ba2TiGe2O8 crystal is an excellent candidate for nonlinear optical crystals. © 2002 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Load/unload displacement curves at room temperature (humidity 49%) for silica glass have been measured in the penetration range of 0.5–1.2 μm using a Vickers nanoindentation technique (load/unload speed 50 mN/s). Deformation energies have been estimated for the first time. The universal (dynamic) hardness, Hu, and elastic recovery, ER, at the penetration depth, ht, of 1.0 μm are Hu= 4.1 GPa and ER= 0.7. The following energies for total deformation, Ut, elastic deformation, Ue, and plastic deformation (i.e., densification during loading), Up, are obtained: Ut=190, Ue=135 and Up= 55 kJ/mol at ht= 0.5 μm and Ut= 139, Ue= 96 and Up= 43 kJ/mol at ht=1.0 μm. All these deformation energies increase with decreasing penetration depth. It is found that plastic deformation energies of 38–55 kJ/mol for 0.5 〈 ht 〈 1.2 μm are very close to the activation energy (46–54 kJ/mol) for the recovery of densification in silica glass, but are very small compared with the single bond strength (443 kJ/mol for Si—O bond) of SiO2.
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  • 9
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The glass formation region, crystalline phases, second harmonic (SH) generation, and Nd:yttrium aluminum garnet (YAG) laser-induced crystallization in the Sm2O3–Bi2O3–B2O3 system were clarified. The crystalline phases of Bi4B2O9, Bi3B5O12, BiBO3, SmxBi1−xBO3, and SmB3O6 were formed through the usual crystallization in an electric furnace. The crystallized glasses consisting of BiBO3 and SmxBi1−xBO3 showed SH generations. The formation of the nonlinear optical BiB3O6 phase was not confirmed. The formation (writing) region of crystal lines consisting of SmxBi1−xBO3 by YAG laser irradiation was determined, in which Sm2O3 contents were∼10 mol%. The present study demonstrates that Sm2O3–Bi2O3–B2O3 glasses are promising materials for optical functional applications.
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Some K2O-Nb2O5-GeO2 glasses are prepared, and their crystallization behaviors are examined. 25K2O·25Nb2O5·50GeO2 glass with the glass transition temperature Tg= 622°3C and crystallization onset temperature Tx= 668°3C shows a prominent nanocrystallization. The crystalline phase is K3,8Nb5Ge3O20,4 with an orthorhombic structure. The sizes of crystals in the crystallized glasses heat-treated at 630° and 720°3C for 1 h are °10 and 20–30 nm, respectively, and the crystallized glasses obtained by heat treatments at 620°-850°3C for 1 h maintain good transparency. The density of crystallized glasses increases gradually with increasing heat-treatment temperature, and the volume fraction of crystals in the sample heat-treated at 630°3C for 1 h is estimated to be ∼35%. The usual Vickers hardness and Martens hardness (estimated by nanoindentation) of 25K2O·25Nb2O5·50GeO2 glass change steeply by heat treatment at Tg, i.e., at around 35% volume fraction of nanocrystals. The present study demonstrates that the composite of nanocrystals and the glassy phase has a strong resistance against deformation during Vickers indenter loading in crystallized glasses.
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