Publication Date:
2021-05-12
Description:
Since 2000, a Thermal Ionisation Mass Spectrometer (Thermo ScientificTM Triton TI® Mass
Spectrometer) and a clean laboratory are operating at the Istituto Nazionale di Geofisica e Vulcanologia
(INGV), Sezione di Napoli, Osservatorio Vesuviano (OV) to measure strontium (Sr) and neodymium (Nd)
isotope compositions of volcanic products for scientific purposes.
In 2014 particular attention has been dedicated to set up the analytical procedure for extracting Sr and
Nd and measuring their isotope compositions from groundwater and mineral water, due to its growing
interest on environmental topics.
Strontium is considered a trace element and Sr2+ preferentially substitutes for Ca2+ in most rock types
since it geochemically behaves like calcium. Groundwater is enriched in Sr during water-rock interaction
processes occurring within the saturated and/or unsaturated zones. Conversely, Sr is removed from water as a
result of mineral precipitation and ion exchange reactions. The most common removal process is the coprecipitation of Sr2+ ions with calcium carbonate. However, this latter process does not fractionate Sr2+
[Faure and Powell, 1972]. Therefore, the Sr isotopic composition of groundwater records an integrated signal
of water-rock interaction along flow path and dissolution/precipitation events, and can be used as a dynamic
tracer to constrain subsurface flow in volcanic, non volcanic and geothermal areas. Water is a natural
resource, which is renewed by different processes. The aforementioned geochemical processes and reactions
with dissolving/precipitating minerals have a profound effect on water quality.
Since the 1990s, Sr isotopes have been extensively used as a natural tracer of groundwater flow
[Peterman and Stuckless, 1992; Bullen et al., 1996; Johnson and De Paolo, 1994; McNutt et al., 1990;
McNutt, 2000; Frost et al., 2002; Gosselin et al., 2004; Klaus et al., 2007] because groundwater
progressively acquires the 87Sr /86Sr isotopic ratio from the rocks with which it has interacted [Prasanna et al.
2009]. Furthermore, variable Sr isotope ratios and concentrations characterize different groundwater sources
and are tracers of groundwater mixing [eg. Carucci et al., 2012].
In this work we present the first results obtained by analyzing the Sr isotope composition of two
mineral waters, selected groundwater samples from Mt. Etna and a certified water sample from North
America (National Research Council Canada - NRC, Certified Reference Materials - CRM TM-25.4). On the
contrary, the Nd isotope ratios of such water samples have been not measured due to the low Nd content of
the investigated samples. A statistically representative data set on certified international standards (NIST
SRM 987, La Jolla and JNdi-1) was used to evaluate the quality of the analytical data produced at the INGVOV Radiogenic Isotope Laboratory since 2014.
This methodological approach will allow us to isotopically characterize different water systems with
the aim to trace back the water-rock interaction and mixing processes in different environments. This
analytical procedure could be exported to other geological contests and applied to other types of waters (e.g.
surface and thermal water).
Description:
INGV
Description:
Published
Description:
1-20
Description:
2V. Struttura e sistema di alimentazione dei vulcani
Description:
3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
Description:
4V. Processi pre-eruttivi
Description:
N/A or not JCR
Keywords:
Sr isotope analysis of water
;
Radiogenic Isotope Laboratory
Repository Name:
Istituto Nazionale di Geofisica e Vulcanologia (INGV)
Type:
article
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