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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 1640-1646 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A calorimetric technique has been developed to simultaneously measure the heat and work of solid deformation. The physical construction of the instrument is similar to previously reported deformation calorimeters which operate as null or compensating devices, utilizing features of differential gas thermometry and hot-wire methods of measuring thermal conductivity. The present method combines the quick response time and high sensitivity of such devices with a direct measurement principle which greatly simplifies data acquisition. Theory and operation of the instrument are discussed and some data on a polyurethane elastomer are presented.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 20 (1985), S. 4583-4592 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Wide-angle X-ray diffraction studies of poly-(p-phenylene benzobisthiazole) fibres from Part 1 of this work were undertaken to examine fibre structural changes associated with the heat treatment process and which contribute to the observed significant enhancement of mechanical properties. Crystallite size perpendicular to the fibre axis increases from approximately 2 nm in as-spun fibres to 10 to 12 nm in fibres heat treated at temperatures above 600
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 26 (1991), S. 1762-1768 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The solubility limits of solutions of poly (p-phenylene benzobisthiazole) (PBZT), poly(ether-ether-ketone), and two nylons (du Pont, Zytel®42 and Zytel®330) in methane sulphonic acid (MSA) were determined by turbidimetric titration with water. The solubilities rank as follows: Zytel®42 〉 Zytel®330 〉 PEEK 〉 PBZT. The coagulation of solutions of these polymers was examined in two limiting case: very slow (exposure to water vapour) and very fast (immersion in a water bath) coagulation rates. The slow coagulation of ternary solutions shows that PBZT may either precipitate first from the composite solutions or coprecipitate with the thermoplastic depending on their relative solubility. The immersion coagulation process can be described by a simple diffusion model and the diffusion coefficient of water in the polymer solution is determined to be on the order of 10−5 cm2s−1. Our results suggest that PBZT will coagulate first from ternary solutions of PBZT, nylon, and MSA during wet-spinning, resulting in a continuous microfibrillar network structure of PBZT followed by the precipitation of nylon.
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  • 6
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A method for preparing composite fibres by infiltrating nylon into swollen poly(p-phenylene benzobisthiazole) (PBZT) fibre is described. PBZT fibre forms a microfibrillar network structure during the coagulation process.In-situ network composite (IC) fibres may be prepared by exchanging the coagulant with a solution containing the desired matrix material. These new composite fibres exhibit nearly identical mechanical properties and similar thermomechanical properties to those of so-called molecular composite (MC) fibres prepared from isotropic solutions of PBZT and nylon in methane sulphonic acid (MSA), The mechanical properties of these fibres were determined before and after heat treatment under tension. The structure of pure PBZT and its composite fibres (ICs' and MCs') were characterized using nitrogen adsorption (Brunauer-Emmett-Teller (BET) experiments), small-angle X-ray scattering, and scanning and transmission electron microscopy (SEM and TEM, respectively). The structure of both composite fibres was found to be a microfibrillar network of PBZT in a matrix of amorphous nylon. The average diameters of the PBZT microfibrils were in the range of 10 to 20 nm forin-situ network composites and approximately 4 nm for molecular composites.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 57-72 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The mechanical anisotropy of an aromatic polyamide fibre, Kevlar 49, was studied in tension, compression and torsion. A new technique involved applying small and defined compressive strains to filaments by bonding them to one side of a beam which is subsequently bent to compress the fibres. Using scanning electron and optical microscopy, fibres were shown to form regularly-spaced helical kink bands at 50 to 60° to the fibre axis after the application of small axial compressive strains. Tensile tests of previously-compressed fibres revealed only a 10% loss in tensile strength, after application of as much as 3% compressive strain. A torsion pendulum apparatus was used to measure the shear modulus and an apparent shear strength of fibres. A loss of tensile strength after the application of large (〉 10%) torsional shear strains coincided with a loss in recoverable shear strain due to longitudinal fibre splitting. Ratios of tensile-to-compressive strength, tensile-to-shear strength and tensile-to-shear moduli of 5∶1, 17∶1, and 70∶1, respectively, were measured for Kevlar 49.
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 57-72 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The mechanical anisotropy of an aromatic polyamide fibre, Kevlar 49, was studied in tension, compression and torsion. A new technique involved applying small and defined compressive strains to filaments by bonding them to one side of a beam which is subsequently bent to compress the fibres. Using scanning electron and optical microscopy, fibres were shown to form regularly-spaced helical kink bands at 50 to 60° to the fibre axis after the application of small axial compressive strains. Tensile tests of previously-compressed fibres revealed only a 10% loss in tensile strength, after application of as much as 3% compressive strain. A torsion pendulum apparatus was used to measure the shear modulus and an apparent shear strength of fibres. A loss of tensile strength after the application of large (〉 10%) torsional shear strains coincided with a loss in recoverable shear strain due to longitudinal fibre splitting. Ratios of tensile-to-compressive strength, tensile-to-shear strength and tensile-to-shear moduli of 5∶1, 17∶1, and 70∶1, respectively, were measured for Kevlar 49.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 20 (1985), S. 2719-2726 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The stress-strain behaviour and morphological features of PBT films before and after heat treatment are reported. PBT films possess extraordinary mechanical properties comparable to those of the fibres. A non-uniform residual stress distribution is proposed to account for the elastic-plastic behaviour of as-extruded films and the subsequent extensive fibrillization during tensile testing or tension heat treatment. Tension heat treatment results in significant axial modulus and tensile strength increase by improving overall sample orientation and lateral crystallite size with concomitant straightening of buckled regions in the film.
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  • 10
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The mechanical properties of PRT films feature an interesting temperature and strain-rate dependence. The elastic modulus and yield behaviour have been studied over a wide temperature range from 30 to 650° C. The onset of a structural reorganization is observed at about 300° C. The dependence of yield stress on strain rate at different temperatures was examined in terms of the Eyring theory of an activated rate process. It was found that the stress activation volume varies with temperature. The overall elastic-plastic behaviour as a function of temperature and strain rate was interpreted in terms of a previously suggested model that incorporates residual stresses in a rigid rod-like polymer. Enhancement of modulus was also observed due to deformation of the films under elevated temperatures, where better molecular orientation and lateral ordering are achieved.
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