ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Dynamic mechanical measurements in a torsional (shear) mode have been used to characterize an unfilled epoxy (Epon 828/m-phenylene diamine) and A series of uniaxial graphite fiber (Hercules types A and HM) composites. In unfilled resins containing an excess of the epoxy component, Mc - the average molecular weight between crosslinks - decreases with increasing temperature and duration of cure, suggesting a temperature-dependent side reaction. In fiber-reinforced composites, the dynamic mechanical response is sensitive to fiber type and curing schedule; elevation of Tg by as much as 45°C has been observed. Comparison of the dynamic data with properties predicted by micromechanical models shows only a fair agreement at room temperature, which rapidly worsens at higher temperatures. Surface treatment of type A fibers gives enhanced interlaminar shear strength (ILSS), both at ambient conditions and after hydrothermal aging. Dynamic data for surface-treated systems during hydrothermal aging show a sharper drop in G′ and increase in tan δ. The dynamic data and ILSS results are interpreted in terms of a balance of polymer-fiber interactions, a weak but widespread preferential adsorption of epoxy oligomers on the graphite basal planes at the fiber surface, and a low concentration of covalent bonds between polymer and fiber-surface-functional groups.
Additional Material:
12 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760221304
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