Publication Date:
2019-04-08
Description:
Semi-volatile and intermediate-volatility organic compounds (SVOCs and IVOCs) from anthropogenic sources are likely to be important precursors of secondary organic aerosol (SOA) in urban airsheds, yet their treatment in most models is based on limited and obsolete data or completely missing. Additionally, gas-phase oxidation of organic precursors to form SOA is influenced by the presence of nitric oxide (NO), but this influence is poorly constrained in chemical transport models. In this work, we updated the organic aerosol model in the UCD/CIT (University of California at Davis/California Institute of Technology) chemical transport model to include (i) a semi-volatile and reactive treatment of primary organic aerosol (POA), (ii) emissions and SOA formation from IVOCs, (iii) the NOx influence on SOA formation, and (iv) SOA parameterizations for SVOCs and IVOCs that are corrected for vapor wall loss artifacts during chamber experiments. All updates were implemented in the statistical oxidation model (SOM) that simulates the oxidation chemistry, thermodynamics, and gas–particle partitioning of organic aerosol (OA). Model treatment of POA, SVOCs, and IVOCs was based on an interpretation of a comprehensive set of source measurements available up to the year 2016 and resolved broadly by source type. The NOx influence on SOA formation was calculated offline based on measured and modeled VOC:NOx ratios. Finally, the SOA formation from all organic precursors (including SVOCs and IVOCs) was modeled based on recently derived parameterizations that accounted for vapor wall loss artifacts in chamber experiments. The updated model was used to simulate a 2-week summer episode over southern California at a model resolution of 8 km. When combustion-related POA was treated as semi-volatile, modeled POA mass concentrations were reduced by 15 %–40 % in the urban areas in southern California but were still too high when compared against “hydrocarbon-like organic aerosol” factor measurements made at Riverside, CA, during the Study of Organic Aerosols at Riverside (SOAR-1) campaign of 2005. Treating all POA (except that from marine sources) to be semi-volatile, similar to diesel exhaust POA, resulted in a larger reduction in POA mass concentrations and allowed for a better model–measurement comparison at Riverside, but this scenario is unlikely to be realistic since this assumes that POA from sources such as road and construction dust are semi-volatile too. Model predictions suggested that both SVOCs (evaporated POA vapors) and IVOCs did not contribute as much as other anthropogenic precursors (e.g., alkanes, aromatics) to SOA mass concentrations in the urban areas (
Print ISSN:
1680-7316
Electronic ISSN:
1680-7324
Topics:
Geosciences
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