Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 2313-2320
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The C+NO2→CO+NO reaction at 300 K has been shown to exhibit a strong ultraviolet chemiluminescence from NO (B 2Πr) and a weak one from NO(A 2Σ+). The NO (B 2Πr)v'=0 production rate was found to be approximately ten times greater than that of NO (A 2Σ+)v'=0. No chemiluminescence either from NO(C 2Πr) or NO (D 2Σ+), however energetically accessible, could be observed. These features are in close agreement with the Cs symmetry correction diagram for this reaction. The nascent vibrational distribution of NO(B 2Πr) was found to be much cooler than the prior statistical one.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448327
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