Electronic Resource
New York, NY
:
Wiley-Blackwell
Helvetica Chimica Acta
61 (1978), S. 2002-2018
ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Mikrolin (8) and dechloromikrolin (9) have been shown to exist as tautomeric mixtures in solution. The structures of mono-O-trifluoroacetyl Mikrolin (10) and di-O-acetyl Mikrolin (11) have been elucidated. The products 15 to 23 from reduction of the metabolites 8 9 with Pd/C and Zn in aqueous acetic acid have been identified. The 13C-NMR. spectra of Mikrolin (8) and dechloromikrolin (9) and their derivatives have been completely assigned Based on the results of incorporation experiments with sodium [1-13C]-, [2-13C]- and [1, 2-13C]-acetate, a biosynthetic pathway is proposed for Mikrolin (8).
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19780610609
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