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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1675-1680 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sheets of medium density polyethylene (MDPE) were extruded through a slit die containing an internal separator. Thus, the melt stream was momentarily split before emerging from the die. A line of separation was evident in the extruded sheets. It is attributed to incomplete welding or healing. Measurements of tear energy Gc revealed that the extruded sheets were anisotropic and that the weld line was extremely weak after extrusion start-up, only about 1/5 of the strength elsewhere. As extrusion continued, the strength of the weld line increased to reach that of the bulk material after about 10 min. This is attributed to an increasing temperature of the melt in the die region, aiding interdiffusion. A sample containing 30% by weight of short glass fibers showed less initial weld-line weakness but the weld line remained weak in this case, even after long extrusion times.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 964-973 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The advantageous use of short-fiber-reinforced thermoplastic (SFRTP) resins in the manufacture of pipe requires that the fiber orientation be controlled and that the surface finish not be adversely affected by the presence of the fibers. It is proposed here that a coextrusion process be combined with the use of a Specially designed, expanding channel die to achieve these objectives. Conventional pipe dies tend to promote the axial orientation of fibers, which has an undesirable effect on the hoop properties of pipe. The use of an expanding channel die promotes fiber orientation in the hoop direction. However, even in this case, there is still a strong component of the shear field near the wall of the die, and in this region, axial orientation still predominates, The use of a three-layer, coextrusion process in which unreinforced resin is used for both the inner and outer layers makes it possible to minimize the shear effects on the fiber orientation in the middle SFRTP layer. At the same time, it provides a smooth, fiber-free pipe surface. A theoretical analysis of this process is presented. The analysis shows that the presence of unreinforced surface layers increases the level and uniformity of fiber orientation. The results of an experimental study of fiber orientation in the middle SFRTP layer are found to be in qualitative agreement with the predictions of the theory.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 1172-1173 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A simple test device is described for subjecting bars to large bending deformations and simultaneously monitoring the bending moment. Examples are given of the elastic bending of a bar of a natural rubber vulcanizate and of the maximum bending moment that molded bars of polyethylene and polypropylene can withstand before the fully-plastic state is attained.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 358-363 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: When a thin-walled rubber tube containing an incompressible fluid is compressed between two parallel plates the internal pressure rise depends on the restraints in the contact regions. When there is no friction in the contact zone the pressure rise is lower than when slip is prevented, so that the tube, regarded as a spring, has a compression stiffness which depends on the frictional conditions. The same considerations apply to the inflation of a tube between fixed parallel plates. In this case unstable inflation sets in at a critical pressure when the interfaces are frictionless; the tube develops a pronounced bulge when this pressure is approached. Simple theoretical relations are derived for the internal pressure and compressive force for both these deformations, and for both boundary conditions, assuming that the rubber is Neo-Hookean in elastic behavior. Experimental measurements on tubes of different dimensions are shown to be in reasonably good quantitative agreement with these theoretical predictions in all cases.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 731-746 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A composite normally consists of a material forming a continuous matrix and a different material in the form of discrete particles. The composite structure is characterized by the proportions of each component, the shape of the particles and their arrangement in space. A generalized way to characterize a particle shape and its position relative to adjacent particles is shown to describe the various geometrical arrangements of two components in space. The components of a composite often have different transport or related properties, i.e., thermal or electrical conductivity, gas permeability, modulus of elasticity, etc. A given property of a composite is a function of the structure of the composite and the corresponding property of each component. Structure-property analytical relationships are presented and compared. A generalized relationship corresponding to a generalized particle is discussed and shown to be practical and realistic.
    Additional Material: 15 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 48-53 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Measurements have been made of the recovery of polyethylene samples from bending deformations of varying severity. The amount of spring-back from a severe bend is quite different for different densities (degrees of crystallinity), especially at short times after release, being much greater for lower-density polyethylenes. Short-term spring-back measurements thus afford a simple and rapid means of determining the approximate density. Immediate recovery is small, 5 to 15 percent, and is in rough accord with expectations for elastic-plastic solids. A major protracted recovery process follows. It is accelerated by raising the temperature, in reasonable agreement with the WLF relation for segmental mobility. It is therefore attributed to retarded molecular motions in the amorphous fraction. Final recovery is greater for lower-density materials, but it is incomplete even after very long times or for mild degrees of bending. Thus, some irreversible processes appear to take place, even when bending strains as low as 3 percent are imposed.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 468-478 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In the application of plastic pipes for fluid transport and for the protection of underground electrical cables, it is desirable to improve mechanical properties, particularly in the hoop direction. The use of orientable reinforcing particles such as chopped glass fibers could make possible such an improvement if the orientation of the fibers could be controlled. While conventional pipe extrusion dies tend to promote axial fiber orientation, the use of an expanding channel die has been proposed to produce a preferential hoop orientation of fibers. In this paper, a theoretical model of the flow of a fiber suspension through an expanding channel die that predicts the fiber orientation distribution at the die exit is described. The effects of Theological properties and die geometry on the final fiber orientation distribution are predicted. The results of an experimental study of fiber orientation in pipe extruded using an expanding channel die are shown to be in agreement with the theoretical predictions.
    Additional Material: 12 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 102-108 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental study of the dynamics of thermoforming a high-impact polystyrene sheet was undertaken to evaluate the effect of evacuation rate and temperature on the rate of sheet deformation and the wall thickness distribution of the molded part. The studies were conducted using an instrumented cylindrical mold having an adjustable bottom insert to vary the depth of draw. The evaculation rate was varied by introducing a flow restriction in the form of an orifice plate in the base of the mold. The deformation rate of the sheet was determined by means of fiber-optic infrared detectors located at various depths within the mold. Mold contact sensors also provided information with regard to the deformation process after contact with the mold surface had been achieved. The evaluation characteristics were monitored by a pressure transducer. A three-level, two-variable factorial design was conducted to provide information of the influence of the principal operating conditions and their interactions on the measured response variables. Reliable predictive expressions were derived for the minimum pressure, time to reach minimum pressure, overall forming time, and wall thickness near the lip of the mold. The wall thickness at other locations around the periphery of the mold contour was found to be relatively insensitive to the rate of evacuation and material temperature.
    Additional Material: 9 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 10 (1989), S. 28-38 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper, a simple theoretical model for elastic properties of short fiber-reinforced thermoplastic (SFRTP) composite systems is described, which considers the effect of two important structural parameters, viz., fiber aspect ratio distribution and fiber orientation distribution. An experimental technique for producing SFRTP samples featuring a fairly uniform fiber orientation is described, and a broad set of experimental results on the mechanical properties of SFRTP systems based on polystyrene (PS) and polyethylene (PE) resins with several fiber loadings is presented. The use of the simple theoretical model to analyze the experimentally-determined elastic properties is discussed.
    Additional Material: 23 Ill.
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