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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of metamorphic geology 23 (2005), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: High-grade gneisses (amphibolite–granulite facies) of the Namche Barwa and Gyala Peri massifs, in the eastern Himalayan syntaxis, have been unroofed from metamorphic depths in the late Tertiary–Recent. Rapid exhumation (2–5 mm year−1) has resulted in a pronounced shallow conductive thermal anomaly beneath the massifs and the intervening Tsangpo gorge. The position of the 300 °C isotherm has been estimated from fluid inclusions using CO2–H2O immiscibility phase equilibria to be between 2.5 and 6.2 km depth below surface. Hence, the near-surface average thermal gradient exceeds 50 °C km−1 beneath valleys, although the thermal gradient is relatively lower beneath the high mountains. The original metamorphic fluid in the gneisses was 〉90% CO2. This fluid was displaced by incursion of brines from overlying marine sedimentary rocks that have since been largely removed by erosion. Brines can exceed 60 wt% dissolved salts, and include Ca, Na, K and Fe chlorides. These brines were remobilized during the earliest stages of uplift at 〉500 °C. During exhumation, incursion of abundant topography-driven surface waters resulted in widespread fracture-controlled hydrothermal activity and brine dilution down to the brittle–ductile transition. Boiling water was particularly common at shallow levels (〈2.5 km) beneath the Yarlung Tsangpo valley, and numerous hot springs occur at the surface in this valley. Dry steam is not a major feature of the hydrothermal system in the eastern syntaxis (in contrast to the western syntaxis at Nanga Parbat), but some dry steam fluids may have developed locally.
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd.
    Journal of metamorphic geology 16 (1998), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Otago and Alpine Schist belts of southern New Zealand have traditionally been treated as structurally continuous metamorphic belts with minor modification by brittle faulting. Mapping of biotite and garnet isograds has been hindered by rock types unfavourable for index mineral growth. Closer examination of well-exposed boundaries between metamorphic zones shows that they juxtapose rocks of different type and structural history. Apparent structural continuity across these zones is due to development of a locally pervasive boundary-parallel foliation on both sides of the boundary, in a broad boundary zone (up to 2 km wide). This feature has implications for mapping and metamorphic petrology in other metamorphic belts, where structural continuity has traditionally been assumed. True metamorphic isograds may be rare, and metamorphic zones may more commonly represent structural slices of complex, tectonically disrupted metamorphic piles.
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 12 (1994), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Calcite and quartz veins have formed, and are forming, in steeply dipping fissures in the actively rising Alpine Schist metamorphic belt of New Zealand. The fluids that deposited these minerals were mostly under hydrostatic pressure almost down to the brittle-ductile transition, which has been raised to 5-6 km depth by rapid uplift. Some fluids were trapped under lithostatic pressures. Fluids in the fissure veins were immiscible H2O + NaCl-CO2 mixtures at 200-350d̀ C. Bulk fluid composition is 15-20 mol% CO2 and 〈4.3 total mol CH4+ N2+ Ar/100mol H2O. Water hydrogen isotopic ratio δDH2O in the fissure veins spans -29 to -68‰, δ18OH2O -0.7 to 8.5‰, and bulk carbon isotopic ratio δ13C ranges from -3.7 to -11.7‰. The oxygen and hydrogen isotopic data suggest that the water has a predominantly meteoric source, and has undergone an oxygen isotope shift as a result of interaction with the host metamorphic rock. Similar fluids were present during cooling and uplift. Dissolved carbon is not wholly derived from residual metamorphic fluids; part may be generated by oxidation of graphite.
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 6 (1988), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Fluids, some of which are CO2-rich (up to 40 mol.% CO2) and some of which are highly saline (up to 18 wt% NaCl equivalent), are trapped as fluid inclusions in quartz-calcite (∼ metallic minerals) veins which cross-cut the pumpellyite-actinolite to amphibolite facies rocks of the Alpine Schist. Fluids were commonly trapped as immiscible liquid-vapour mixes in quartz and calcite showing open-space growth textures. Fluid entrapment occurred at fluid pressures near 500 bars (possibly as low as 150 bars) at temperatures ranging from 260 to 330° C. Saline fluids may have formed by partitioning of dissolved salts into an aqueous phase on segregation of immiscible fluids from a low-density CO2-rich fluid. Calcite deposited by these fluids has δ13C ranging from – 8.4 to – 11.5 and δ18O from + 4 to + 13. Isotopic data, fluid compositions and mode of occurrence suggest that the fluids are derived from high-grade metamorphic rocks. Fluid interaction with wall-rock has caused biotite crystallization and/or recrystallization in some rocks and retrogression of biotite to chlorite in other rocks.Fluid penetration through the rock is almost pervasive in many areas where permeability, probably related to Alpine Fault activity, has focussed fluids on a regional scale into fractured rocks. The fluid flow process is made possible by high uplift-rates (in excess of 10 mm/year) bringing hot rocks near to the surface.
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of metamorphic geology 11 (1993), S. 0 
    ISSN: 1525-1314
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Abstract Deformed quartz veins in garnet-zone schist adjacent to the active Alpine Fault, New Zealand, have fluid inclusions trapped along quartz grain boundaries. Textures suggest that the inclusions formed in their present shapes during annealing of the deformed veins. Many of the inclusions are empty, but some contain carbon dioxide with densities that range from 0.16 to 0.80 g cm−3. No water, nitrogen or methane was detected. The inclusions are considerably more CO2-rich than either the primary metamorphic fluid (〈5% CO2) or fluids trapped in fracture-related situations in the same, or related, rocks (〈50% CO2). Enrichment of CO2 is inferred to have resulted from selective migration (wicking) of saline water from the inclusions along water-wet grain boundaries after cooling-induced immiscibility of a water-CO2 mixture. Inclusion volumes changed after loss of water. Non-wetting CO2 remained trapped in the inclusions until further percolation progressively removed CO2 in solution. This mechanism of fluid migration dominated in ductile quartz-rich rocks near, but below, the brittle-ductile transition. At deeper levels, hydraulic fracturing is also an important mechanism for fluid migration, whereas at shallower levels advection through open fractures dominates the fluid flow regime.
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Earth and Planetary Science Letters 103 (1991), S. 1-9 
    ISSN: 0012-821X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Earth and Planetary Science Letters 128 (1994), S. 169-182 
    ISSN: 0012-821X
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 39 (2000), S. 875-887 
    ISSN: 1432-0495
    Keywords: Key words Marcasite ; Cinnabar ; Phosphates ; Hot springs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Northland, New Zealand has been affected by natural hot water spring systems depositing elevated concentrations of mercury and arsenic over the past 5 million years. Due to the different erosion levels of these hot water systems, four principal types of mercury and arsenic occurrences are found: active hot springs; layered surface deposits (sinters) deposited by hot springs; highly fractured rock zones formed immediately beneath hot springs; and chemically altered and mineralized rock from the deeper roots of hot spring systems. Mercury occurs principally as cinnabar and as a minor impurity (〈1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Mercury is irregularly distributed through limonitic cements formed during oxidation. Arsenic occurs as a minor impurity (〈1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Arsenic is also variably dispersed through limonite, but not necessarily with mercury. Decomposition of marcasite constitutes the most significant source of mercury and arsenic pollution from the studied sites. Release of mercury and arsenic into the environment from marcasite, phosphates and limonite is enhanced by acidification of the sites (down to pH of 2), caused by oxidation of iron sulfides. Mercury and arsenic concentrations of up to 100 parts per billion should be expected in waters near the deposits; these concentrations are in excess of recommended drinking water levels.
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 25 (1990), S. 118-125 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Southern Alps of New Zealand is an actively rising mountain belt which displays a thermal anomaly adjacent to the Alpine Fault, the Australian-Pacific plate boundary. Extensive fluid movement occurs in this uplift zone, resulting in metallic vein mineralization. Gold mineralization is confined to greenschist facies rocks, while younger veins in amphibolite facies rocks near the Alpine Fault are enriched in copper. Transport and deposition of metals in this complex hydrothermal system is governed by interaction between rising metamorphic fluids and downward-percolating meteoric fluid. Metamorphic fluids have equilibrated with graphitic schist country rock and are relatively reduced. Infiltration and mixing of meteoric water increases oxygen activity and decreases sulphur activity in the fluid. Oxidised meteoric water heats up and dissolves Cu during downward percolation. This Cu is deposited as the fluid becomes more reduced. Hence, there is a progressive increase in copper content in the middle portions of the hydrothermal system, especially in the more permeable highly fractured rocks near the Alpine Fault.
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 25 (1990), S. 281-288 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A prominent set of veins was formed during post-metamorphic deformation of the Caledonian Dalradian metamorphic belt. These veins are concentrated in dilational zones in fold hinges, but apophyses follow schistosity and fold axial surface fractures. The veins are most common in the cores of regional structures, especially the Dalradian Downbend and consist of quartz, calcite, chlorite and metallic sulphides and oxides. Metals, including gold, have been concentrated in the veins. The fluid which formed the veins was low salinity (1–5 wt% NaCl and KCl) CO2-bearing (3–16 wt% CO2) water of metamorphic origin. The fluid varies slightly in composition within and between samples, but is essentially uniform in composition over several hundred km2. Vein formation occurred at about 350±50 °C and 200–300 MPa pressure. Further quartz mineralization occurred in some dilational zones at lower temperatures (160–180 °C). This later mineralization was accompanied by CO2 immiscibility. Dilution and oxidation of the metamorphic fluid occurred due to mixing with meteoric water as the rocks passed through the brittle-ductile transition. A similar metamorphic fluid is thought to have been responsible for gold mineralization in the nearby Tyndrum Fault at a later stage in the Dalradian uplift.
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