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    Publication Date: 2020-12-14
    Description: In the last few decades, advanced monitoring networks have been extended to the main active volcanoes, providing warnings for variations in volcano dynamics. However, one of the main tasks of modern volcanology is the correct interpretation of surface-monitored signals in terms of magma transfer through the Earth's crust. In this frame, it is crucial to investigate decompression-induced magma degassing as it controls magma ascent towards the surface and, in case of eruption, the eruptive style and the atmospheric dispersal of tephra and gases. Understanding the degassing behaviour is particularly intriguing in the case of poorly explored evolved alkaline magmas. In fact, these melts frequently feed hazardous, highly explosive volcanoes (e.g., Campi Flegrei, Somma-Vesuvius, Colli Albani, Tambora, Azores and Canary Islands), despite their low viscosity that usually promotes effusive and/or weakly explosive eruptions. Decompression experiments, together with numerical models, are powerful tools to examine magma degassing behaviour and constrain field observations from natural eruptive products and monitoring signals. These approaches have been recently applied to evolved alkaline melts, yet numerous open questions remain. To cast new light on the degassing dynamics of evolved alkaline magmas, in this study we present new results from decompression experiments, as well as a critical review of previous experimental works. We achieved a comprehensive dataset of key petrological parameters (i.e., 3D textural data for bubbles and microlites using X-ray computed microtomography, glass volatile contents and nanolite occurrence) from experimental samples obtained through high temperature-high pressure isothermal decompression experiments on trachytic alkaline melts at super-liquidus temperature. We explored systematically a range of final pressures (from 200 to 25 MPa), decompression rates (from 0.01 to 1 MPa s−1), and volatile (H2O and CO2) contents. On these grounds, we integrated coherently literature data from decompression experiments on evolved alkaline (trachytic and phonolitic) melts under various conditions, with the aim to fully constrain the degassing mechanisms and timescales in these magmas. Finally, we simulated numerically the experimental conditions to evaluate strengths and weaknesses in decrypting degassing behaviour from field observations. Our results highlight that bubble formation in evolved alkaline melts is primarily controlled by the initial volatile (H2O and CO2) content during magma storage. In these melts, bubble nucleation needs low supersaturation pressures (≤ 50–112 MPa for homogeneous nucleation, ≤ 13–25 MPa for heterogeneous nucleation), resulting in high bubble number density (~ 1012–1016 m−3), efficient volatile exsolution and thus in severe rheological changes. Moreover, the bubble number density is amplified in CO2-rich melts (mole fraction XCO2 ≥ 0.5), in which continuous bubble nucleation predominates on growth. These conditions typically lead to highly explosive eruptions. However, moving towards slower decompression rates (≤ 10−1 MPa s−1) and H2O-rich melts, permeable outgassing and inertial fragmentation occur, promoting weakly explosive eruptions. Finally, our findings suggest that the exhaustion of CO2 at deep levels, and the consequent transition to a H2O-dominated degassing, can crucially enhance magma vesiculation and ascent. In a hazard perspective, these constraints allow to postulate that time-depth variations of unrest signals could be significantly weaker/shorter (e.g., minor gas emissions and short-term seismicity) during major eruptions than in small-scale events.
    Description: Published
    Description: 103402
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2021-03-03
    Description: The Campanian Plain (CP) shallow aquifer (Southern Italy) represents a natural laboratory to validate geochemical methods for differentiating diffuse anthropogenic pollution from natural water-rock interaction processes. The CP is an appropriate study area because of numerous potential anthropogenic pollution vectors including agriculture, animal husbandry, septic/drainage sewage systems, and industry. In order to evaluate the potential for geochemical methods to differentiate various contamination vectors, 538 groundwater wells from the shallow aquifer in Campanian Plain (CP) were sampled. The dataset includes both major and trace elements. Natural water-rock interactions, which primarily depend on local lithology, control the majority of geochemical parameters, including most of the major and trace elements. Using prospective statistical methods in combination with the traditional geochemical techniques, we determined the chemical variables that are enriched by anthropogenic contamination (i.e. NO3, SO4 and U) by using NO3 as the diagnostic variable for detecting polluted groundwater. Synthetic agricultural fertilizers are responsible for the majority of SO4 and U pollution throughout the CP area. Both SO4 and U are present in the groundmass of synthetic fertilizers; the uranium concentration is specifically applicable as a tracer for non-point source agricultural fertilizer contamination. The recognition of non-geological (anthropogenic) inputs of these elements has to be considered in the geochemical investigations of contaminated aquifers.
    Description: Published
    Description: 46
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 6
    Publication Date: 2020-11-30
    Description: Magma-carbonate interactions and the subsequent CO2 release can occur before and during an eruption, critically affecting magma storage and ascent processes. However, the mechanisms and timescales of those interactions are unclear, particularly during the fast magma withdrawal that feeds high-intensity eruptions. In order to better understand magma‑carbonate interactions, we selected the caldera-forming Pomici di Base plinian eruption, the oldest (22 ka) and largest (〉 4.4 km3) explosive event in the history of the Somma-Vesuvius volcanic system, as case study. During this event the emission of trachytic and latitic-shoshonitic (~25% and ~75% of the erupted magma volume respectively) magmas generated a long-lasting plinian column, hypothetically driven by CO2 liberation during magma‑carbonate interaction. In this study, we reconstruct in detail the evolution of the plumbing system during the Pomici di Base eruption combining geochemical (major/minor elements and radiogenic/stable isotopes) analyses of juvenile products with thermodynamic and kinetic calculations. Our results demonstrate that magmatic stoping (i.e., the formation and transport of host-rock pieces into a magma body) during caldera collapse evolution can promote rapid magma assimilation of carbonate blocks and CO2-rich fluids resulting from destabilization of the carbonate bedrock, thus triggering CO2 release and acting as a fuel for the eruption explosivity, especially when residual hot mafic magmas are involved. Our findings suggest that the accurate knowledge of these processes and their influence on eruptive dynamics are critical for improving the hazard assessments of volcanoes with plumbing systems located in carbonate bedrocks.
    Description: Published
    Description: 105628
    Description: 1V. Storia eruttiva
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 7
    Publication Date: 2020-05-05
    Description: The reconstruction of the pre-eruptive storage conditions as well as syn-eruptive magma ascent dynamics of past eruptions is of fundamental importance to decipher the relationship between surface-monitored signals and the sub-volcanic processes in order to learn more about the eruptive behaviour of active volcanoes. The Pomici di Base Plinian eruption is the first (22 ka) and largest (〉 4.4 km3 ) event of the SommaVesuvius volcanic complex. Here we present the preliminary results of a geochemical, isotopic, two-dimensional and three-dimensional textural study performed on volcanic products emitted during the Plinian phase of this eruptive event with the aim to reconstruct in more details the magmatic evolution of this large caldera-forming eruption. Particularly, it was fed by chemically and thermally zoned magmas extracted from a crystal mush zone in a magma chamber with top at ~4.5 km depth. During this eruption, crustal (limestone) contamination and subsequent CO2 emissions as well as changes in degassing mechanisms mainly controlled the eruptive dynamics.
    Description: Published
    Description: 23-40
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Somma-Vesuvius, Plinian eruptions, magma storage and ascent. ; petrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 8
    Publication Date: 2019-02-06
    Description: Trigger mechanisms and syn-eruptive processes of Plinian eruptions are poorly understood especially in the case of mafic powerful events. In the last decades, the combined geochemical and textural studies on volcanic rocks have proven to be fundamental tools for exploring the dynamics of magma ascent in volcanic conduits and for improving our ability to interpret volcano-monitoring signals and assess hazard. In this case study, we quantitatively investigate 2D and 3D micro-textural, geochemical, and isotopic features of pyroclastic rocks erupted during the Pomici di Base Plinian eruption (22 ka), the generally acknowledged first and most powerful event of the Somma–Vesuvius volcano. A peculiar aspect of this eruption is its high intensity that remained stable during the entire Plinian phase despite the strong magma compositional variation towards mafic terms. We infer that the transfer of magma towards the surface was intensified by the occurrence of rapid vesiculation pulses driven by limestone assimilation (skarn recycling) during magma ascent through the carbonatic bedrock. We conclude that limestone assimilation can hence be a syn-eruptive process, able to trigger further gas nucleation with deep impact on the eruption intensity, particularly crucial in the case of mafic/intermediate magma compositions.
    Description: Published
    Description: id 61
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Somma-Vesuvius ; solid earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 9
    Publication Date: 2021-09-08
    Description: The explosive volcanic event of the 1538 AD Monte Nuovo eruption (Volcanic Explosivity Index, VEI = 2) in the Campi Flegrei high-risk caldera (Italy) has a strategic significance in the framework of volcanology and volcanic hazard of caldera-forming magmatic systems. In fact, it represents the last and unique historical eruption of the highly populated Phlegraean restless-caldera, and its precursory and eruptive phenomena are well-known because they were described in detail by contemporaneous eyewitnesses. In this study, a set of samples representative of the complete stratigraphic sequence of the Monte Nuovo eruption was characterized using phase-contrast synchrotron radiation computed microtomography and quantitatively investigated through the development of a new protocol for 3D textural analysis of highly-vesiculated volcanic rocks. Previous studies of products from this eruption are available in the literature, mostly based on 2D imaging techniques, and thus provide a useful data set for comparison. The 3D textural measurements allow us to investigate the subvolcanic processes (mechanisms and timing of magma degassing) that occurred during magma ascent in the conduit for each stage of the eruption and their relationship with the variations in the eruptive style described in the contemporaneous accounts of the eruption. This information is fundamental for the definition of a volcanic eruption scenario for such low-VEI events, often recurrent in the history of the caldera, and is useful both for hazard assessment and emergency planning.
    Description: Published
    Description: 316-331
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 10
    Publication Date: 2022-03-16
    Description: The Campi Flegrei caldera is considered the most dangerous volcano in Europe and is currently in a new phase of unrest (started in 2000 and still ongoing) that has persisted intermittently for several decades (main crisis occurred from 1950-52, 70-72 and 82-84). Here, by combining the petrological and geochemical data collected in recent decades with numerical simulations, we place new constraints on the source(s) of the current dynamics of the volcano. In particular, we show that the measured (N2-He-CO2) geochemical changes at the fumaroles of Solfatara hydrothermal site are the result of massive (about 3 km3) magma degassing in the deep portion (≥ 200 MPa, 8 km of depth) of the plumbing system. This degassing mechanism would be able to flood the overlying hydrothermal system with hot gas, thus heating and fracturing the upper crust inducing shallow seismicity and deformation. This implies that the deep magma transfer process (≥8 km) has been decoupled from the source of deformation and seismicity, localized in the first kilometers (0-4 km) of caldera-filling rocks. This information on magma transfer depth can have important implications for defining the best monitoring strategies and for forecasting a future eruption. Finally, this study highlights how petrological and geochemical data allow us to explore the dynamics of the deep portion of the plumbing system and thus trace the occurrence of recharge episodes, in a portion of the ductile lower crust where magma transfer occurs in the absence of earthquakes. Plain Language Summary Calderas are volcanic depressions formed as the ground collapses during huge volcanic eruptions. They often exhibit pronounced unrest, with frequent earthquakes, ground uplift, and considerable heat and mass flux that are monitored by volcanologists for eruption forecasting. However, as this activity is due to the complex interactions among magma and hydrothermal system stored beneath the volcano, it is always difficult to predict the evolution of the unrest towards critical conditions until to eruption. The Campi Flegrei caldera is among the most dangerous volcanos in Europe and is currently in a new phase of unrest that has lasted for several decades, whose nature (magmatic or not magmatic) has remained unclear. Here, we combine petrological and geochemical observations collected in recent decades with numerical simulations to place new constraints on the source of the recent dynamics of the volcano. In particular, we show that new deep magma has recharged the shallow reservoir beneath the volcano and flooded the overlying hydrothermal system with hot gas; thereby weakening the upper rocks allowing deformation (ground uplift) and fracturing (seismicity). This information is particularly important in the case of high-risk Campi Flegrei caldera, because it can help to improve defense strategies in case of future eruption.
    Description: Published
    Description: e2021JB023773
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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