ISSN:
1434-4475
Keywords:
Gallium-chloro complexes
;
71Ga-NMR
;
Raman spectroscopy
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Using aqueous GaCl3 and chloride containing Ga(ClO4)3 solutions measurements have been carried out to investigate the formation of complexes with mixed ligands beside the [GaCl4]− ion. In contrast to the Raman spectra, which contain only the signals of the [GaCl 4 − ] and the [Ga(H2O)6]3+ ion, the71Ga-NMR spectra give clear evidence for the existence of complexes with mixed ligands. Investigations at low temperatures showed their coordination to be octahedral resulting in species [GaCln(H2O)6−n ](3−n)+.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00810938
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