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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 411 (2001), S. 536-537 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The properties of the Earth's mantle change abruptly 660 km below the surface, with sharp rises in both density and the transmission speed of seismic waves created by earthquakes. But in 1998 it was announced that highly sophisticated laboratory experiments had failed to confirm this 660 km ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 408 (2000), S. 844-847 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] During the subduction of oceanic lithosphere, water is liberated from minerals by progressive dehydration reactions and is thought to be critical to several geologically important processes such as island-arc volcanism, intermediate-depth seismicity and chemical exchange between the subducting ...
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillan Magazines Ltd.
    Nature 392 (1998), S. 650-653 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Near a depth of 410 km, the speeds at which seismic waves travel in Earth's mantle rise sharply, an observation long attributed to high-pressure transformation of the mineral olivine to wadsleyite. However, seismological studies of this ‘410-km discontinuity’ reveal wave-speed increases ...
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 324 (1986), S. 449-451 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The 400-km seismic discontinuity reflects a change in elastic properties of the mantle and has been attributed to a phase transformation of olivine to a spinel-like structure at high pressures1. Subsequent work has given rise to a generally accepted model in which the discontinuity is attributed to ...
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 141 (1993), S. 101-109 
    ISSN: 1420-9136
    Keywords: Seismic discontinuities ; phase transitions ; elastic properties ; equations of state ; velocity contrasts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Seismologically determined properties of the 400 km discontinuity may be compared to experimentally determined properties of the associated phase transformation in order to place constraints upon upper mantle bulk composition. Disagreement among previous studies is commonly ascribed to differences in elastic equations of state (especially to assumptions about pressure and temperature derivatives) between studies. However, much of the disparity between studies is actually due to the selection of different seismic data functionals (P-wave velocity,S-wave velocity, etc.) for comparison to minnral clasticity calculations, rather than to the differences in elasticity data sets and equations of state. Within any given study, bulk sound velocity comparisons generally yield more olivine-rich compositional estimates than doP-wave velocity comparisons, which in turn indicate more olivine thanS-wave velocities. Indeed, such variation in compositional estimates within a given study (arising from choice of data functional) exceeds the variation between studies (arising from elastic equation of state approx mations). it can be argued that bulk sound velocities are better constrained seismologically than densities and, being independent of assumptions about shear moduli, should provide more reliable compositional estimates thanP-orS-wave velocities. Using recently measured bulk and shear moduli equations of state, mutually consistent estimates of upper mantle olivine content can be obtained fromP-wave,S-wave, and bulk sound velocity contrasts at 400 km only if ∂ ln μ/∂T of β has a value of about−2×10−4K−1, yielding approximately 52% olivine by volume. A value of ∂ ln μ/∂T smaller in magnitude would require reassessment of several underlying assumptions.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 22 (1995), S. 375-382 
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract We examine thermoelastic equations of state for silicate perovskite based on data from recent static compression studies. We analyze trade-offs among the fitting parameters and examine data sets for possible effects of metastability and of Mg-Fe solid solution. Significant differences are found between equations of state based on low pressure measurements obtained for perovskite outside of its stability field. Increasingly consistent results are obtained when higher pressure data are used, despite differences in the zero-pressure parameters used to describe the equations of state. The results highlight the importance of measuring the thermoelastic properties of perovskite at high pressure, specifically within its stability field, and the potential problems associated with large extrapolations of equations of state in the analysis of seismic data.
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of seismology 2 (1998), S. 65-86 
    ISSN: 1573-157X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Through a detailed analysis of seismicity at the base of the transition zone, we obtain an updated value of the maximum reliable depth of confirmed seismicity, we investigate regional variation in the maximum depth of seismicity among those Wadati-Benioff zones which reach the bottom of the transition zone, and we attempt to quantify the maximum possible rate of seismic release in the lower mantle compatible with the failure to detect even a single event since the advent of modern seismological networks. We classify deep subduction zones into three groups: those whose seismicity does not reach beyond 620 km, those whose seismicity appears to terminate around 650–660 km, and Tonga-Kermadec (and the ‘Vityaz’ cluster) whose seismicity extends to 685–690 km. We suggest that the depth extent of seismicity is controlled by the depth of the γ → pv + mw transition responsible for the ‘660-km’ seismic discontinuity, which is deflected to greater depths in cold slabs than in warmer ones. We note that this transition marks the depth below which thermal perturbation of phase transitions no longer generates buoyancy anomalies and their large attendant down-dip compressive stresses and below which strain energy generated by other mechanisms may not accumulate to seismogenic levels due to superplastic weakness in fine-grained materials. We find that the maximum level of seismic activity in the lower mantle must be at least three orders of magnitude less than that observed in the transition zone.
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  • 8
    Publication Date: 2019-04-01
    Description: Diamond is a wide-bandgap semiconductor possessing exceptional physical and chemical properties with the potential to miniaturize high-power electronics. Whereas boron-doped diamond (BDD) is a well-known p-type semiconductor, fabrication of practical diamond-based electronic devices awaits development of an effective n-type dopant with satisfactory electrical properties. Here we report the synthesis of n-type diamond, containing boron (B) and oxygen (O) complex defects. We obtain high carrier concentration (∼0.778 × 1021 cm−3) several orders of magnitude greater than previously obtained with sulfur or phosphorous, accompanied by high electrical conductivity. In high-pressure high-temperature (HPHT) boron-doped diamond single crystal we formed a boron-rich layer ∼1–1.5 μm thick in the {111} surface containing up to 1.4 atomic % B. We show that under certain HPHT conditions the boron dopants combine with oxygen defects to form B–O complexes that can be tuned by controlling the experimental parameters for diamond crystallization, thus giving rise to n-type conduction. First-principles calculations indicate that B3O and B4O complexes with low formation energies exhibit shallow donor levels, elucidating the mechanism of the n-type semiconducting behavior.
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
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  • 9
    Publication Date: 1991-07-01
    Print ISSN: 0022-1376
    Electronic ISSN: 1537-5269
    Topics: Geosciences
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  • 10
    Publication Date: 2018-07-27
    Description: Mapping the spatial distribution of water in the mantle transition zone (MTZ, 410- to 660-km depth) may be approached by combining thermodynamic and experimental mineral physics data with regional studies of seismic velocity and seismic discontinuity structure. HyMaTZ (Hydrous Mantle Transition Zone) is a Python program with graphical user interface, which calculates and displays seismic velocities for different scenarios of hydration in the MTZ for comparison to global or regional seismic-velocity models. The influence of water is applied through a regression to experimental data on how H2O influences the thermoelastic properties of (Mg,Fe)2SiO4 polymorphs: olivine, wadsleyite, and ringwoodite. Adiabatic temperature profiles are internally consistent with dry phase proportion models; however, modeling hydration in HyMaTZ affects only velocities and not phase proportions or discontinuity structure. For wadsleyite, adding 1.65 wt% H2O or increasing the iron content by 7 mol% leads to roughly equivalent reductions in VS as raising the temperature by 160 K with a pyrolite model in the upper part of the MTZ. The eastern U.S. low-velocity anomaly, which has been interpreted as the result of dehydration of the Farallon slab in the top of the lower mantle, is consistent with hydration of wadsleyite to about 20% of its water storage capacity in the upper MTZ. Velocity gradients with depth in absolute shear velocity models are steeper in all seismic models than all mineralogical models, suggesting that the seismic velocity gradients should be lowered or varied with depth and/or an alternative compositional model is required. ©2018. American Geophysical Union. All Rights Reserved.
    Electronic ISSN: 1525-2027
    Topics: Chemistry and Pharmacology , Geosciences , Physics
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