ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary The monomer 6-thiabicyclo[3.2.2.02,4]non-8-ene (4) was prepared by LiAlH4 reductive dechlorination of the 1∶1 adduct3 formed on heating cycloheptatriene with thiophosgene. Cationic initiated polymerization of4 with boron trifluoride etherate as catalyst gave a white solid polymer (8, ¯Mn = 6,300), in 83% yield. The polymer structure was established by comparison of the1H NMR spectrum with that of the model compound 5-mercaptobicyclo[4.1.0]hept-3-ene-2-methanol (6).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00955570
Permalink