ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The tetradentate N2S2 Schiff base ligand 3,3′-[2,2′-(ethylenedioxy)dibenzylidene]bis(S-methyl dithiocarbazate) (H2L), prepared by the condensation of S-methyl dithiocarbazate with 1,4-bis(2-formylphenyl)-1,4-dioxabutane in a 1:2 molar ratio, reacts with nickel acetate to form the title neutral metal complex, [Ni(C20H20N4O2S4)]. The X-ray structure of the complex shows a distorted square-planar geometry around the Ni atom. The monomeric units are weakly associated into dimers via a long Ni...S interaction [3.569 (1) Å]. These dimeric units are then linked by C—H...S intermolecular contacts to form a polymeric chain along the a axis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101001585
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