ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The 2-carbamoylethyl and 2-(methylcarbamoyl)ethyl groups in the title cobaloxime complexes, [Co(C4H7N2O2)2(C3H6NO)(C12H13N)]·C2H6O and [Co(C4H7N2O2)2(C4H8NO)(C10H13NO2)], were isomerized to 1-carbamoylethyl and 1-(methylcarbamoyl)ethyl groups, respectively, on exposure to visible light in the solid state. Although both the crystal structures and the intermolecular hydrogen bonds are different in the two crystals, similar reaction rates were observed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S010827010000826X
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