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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Spectrochimica Acta Part B: Atomic Spectroscopy 49 (1994), S. 683-690 
    ISSN: 0584-8547
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 359 (1997), S. 317-325 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The progress possible in the analysis of refractory powders such as ZrO2, SiC and Al2O3 by the use of new sample preparation, processing and introduction techniques elaborated for AAS, ICP-OES and ICP-MS with low and high mass resolution is demonstrated. For optimized sample preparation techniques based on dissolution of ZrO2, e.g. fusion with (NH4)2SO4, it is shown to what extent impurities present in (NH4)2SO4 determine the detection limit. Hydraulic high pressure nebulization with and without matrix removal by complexing the impurities with dithiocarbamates (Cu, Co, Cr and Ni) or oxine (Fe, Mn and Mo) and fixing them on a C18 solid phase for subsequent solid phase extraction coupled with flame atomic absorption was used to determine Fe, Cu, Cr, Mn, Ni, Co and Mo impurities in (NH4)2SO4 in the 10–100 ng/g range. Further a method to synthesize (NH4)2SO4 with higher purity than some commercially available high-purity (NH4)2SO4 with respect to Fe, Cu, Cr and Mn using high-purity NH3 and chlorosulphonic acid is shown. Reliable determinations of Fe and Al at the 100 μg/g level in ZrO2 with ICP-OES with matrix removal as well as with ICP-MS without matrix removal are reported. For the direct analysis of Al2O3 powders, slurry nebulization ICP-MS sample introduction is shown to improve detection limits and to reduce sample preparation, if the leachable and non-leachable fractions are analyzed separately. For powders such as SiC, the matrix or solvents can cause spectral interferences. Matrix removal is shown to be useful to improve detection limits for the interfered elements. High resolution ICP-MS can be used to control the completeness of matrix removal techniques and to overcome limitations due to spectral interferences even in case of complex materials.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 349 (1994), S. 20-25 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The use of plasma atomic spectrometric methods for the analysis of high-purity refractory powders of Al2O3, SiC and ZrO2 used in the production of advanced ceramics is discussed. Special reference is given to the use of combined procedures including sample decomposition and in the case of ZrO2 to matrix removal as well as to the slurry technique as a direct method in atomic spectrometry with inductively coupled plasmas (ICP). Both the possibilities, limitations and analytical use of the slurry technique are discussed and shown to be related to the particle size of the powder; this should be below the 5–10 μm level. The use of a Simplex method for the optimization of the slurry technique towards obtaining both the highest power of detection and calibration using solutions will be treated for the case of SiC. A critical evaluation of the use of ICP atomic emission and of ICP mass spectrometry is presented.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 351 (1995), S. 110-116 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract ICP-MS has been employed for the analysis of silicon carbide powders in connection with high pressure acid decomposition without and with matrix removal by evaporation. The powder is decomposed by treatment of a 250 mg sample with a mixture of HNO3, H2SO4 and HF. Prior to the analyses with ICP-MS the solutions have to be diluted to a matrix concentration of 500 μg/ml related to SiC in order to realize full long-term precision. The results obtained for Li, B, Na, Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, Ga, Sr, Y, Zr, Nb, Ag, Cd, In, Sn, Sb, Ba, La, Ce, Pr, Nd, Hf, Ta, W, Tl, Pb, Bi, Th and U in SiC powder S-933 are shown to be in good agreement with those of independent methods, such as INAA, ICP-AES with slurry atomization and ICP-AES subsequent to sample decomposition. For extending the use of ICP-MS to elements such as Mg, Ca, Sc and Ti at the relevant concentrations in SiC powders, a more effective matrix removal by evaporation of the decomposition solution to near dryness has been successfully applied. Its advantages have been proven by the results of high resolution ICP-MS. It has been found by analyses of the treated sample solutions for the residual Si and C with ICP-MS that over 99% of the matrix and also of the acids used for decomposition are removed. For B, Al and Fe losses were found to occur at concentration levels of some μg/g, 200 μg/g and 300 μg/g, respectively, and all other elements were detected with very good recoveries. For all 36 elements investigated in this work the detection limits could be improved from the ng/g to the pg/g range by removal of the matrix. The analytical range could be improved, in particular for In, Tl, Bi and U.
    Type of Medium: Electronic Resource
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  • 5
    Publication Date: 2018
    Description: 〈span〉〈div〉Summary〈/div〉The non-linear interaction of ocean surface waves produces coherent infrasound noise—microbaroms—between 0.1 and 0.5 Hz. Microbaroms propagate through the atmosphere over thousands of kilometres due to low absorption and efficient ducting between the ground and the stratopause. These signals are globally and permanently detected by the International Monitoring System (IMS) infrasound network, which has been established to monitor compliance with the Comprehensive Nuclear-Test-Ban Treaty. At the International Data Centre (IDC) in Vienna, where IMS data are routinely processed, microbarom detections appear in overlapping frequency bands, and are treated as false alarms. Therefore, understanding the variability in microbarom detections is essential to support the IDC in the reduction of the false alarm rate. In this study, microbarom amplitudes and the direction of arrivals at the German infrasound station IS26 were modelled. For the simulations, the source was described by an operational ocean wave interaction model, and the signal amplitude was modelled using a semi-empirical attenuation relation. This relation strongly depends on middle atmosphere (MA; i.e. 15–90 km altitude) dynamics; however, vertical temperature and wind profiles, provided by numerical weather prediction (NWP) models, exhibit significant biases and differences when compared with high-resolution lidar soundings in altitudes where infrasound signals propagate. To estimate uncertainties in the modelled amplitude, a fully autonomous lidar for MA temperature measurements was installed at IS26. Temperature and wind perturbations, considering observed biases and deviations, were added to the operational high-resolution atmospheric model analysis produced by the European Centre for Medium-Range Weather Forecasts. Such uncertainties in horizontal winds and temperature strongly impact propagation conditions, explaining almost 97 per cent of the actual detections, compared to 77 per cent when using the direct output of the NWP model only. Incorporating realistic wind and temperature uncertainties in NWP models can thus significantly improve the understanding of microbarom detections as well as the detection capability of a single station throughout the year.〈/span〉
    Print ISSN: 2051-1965
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 6
    Publication Date: 1994-07-01
    Print ISSN: 0584-8547
    Electronic ISSN: 1873-3565
    Topics: Chemistry and Pharmacology , Physics
    Published by Elsevier
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  • 7
    Publication Date: 2018
    Description: 〈span〉〈div〉SUMMARY〈/div〉The nonlinear interaction of ocean surface waves produces coherent infrasound noise—microbaroms—between 0.1 and 0.5 Hz. Microbaroms propagate through the atmosphere over thousands of kilometres due to low absorption and efficient ducting between the ground and the stratopause. These signals are globally and permanently detected by the International Monitoring System (IMS) infrasound network, which has been established to monitor compliance with the Comprehensive Nuclear-Test-Ban Treaty. At the International Data Centre (IDC) in Vienna, where IMS data are routinely processed, microbarom detections appear in overlapping frequency bands, and are treated as false alarms. Therefore, understanding the variability in microbarom detections is essential to support the IDC in the reduction of the false alarm rate. In this study, microbarom amplitudes and the direction of arrivals at the German infrasound station IS26 were modelled. For the simulations, the source was described by an operational ocean wave interaction model, and the signal amplitude was modelled using a semi-empirical attenuation relation. This relation strongly depends on middle atmosphere (MA; i.e. 15–90 km altitude) dynamics; however, vertical temperature and wind profiles, provided by numerical weather prediction (NWP) models, exhibit significant biases and differences when compared with high-resolution light detection and ranging instrument (lidar) soundings in altitudes where infrasound signals propagate. To estimate uncertainties in the modelled amplitude, a fully autonomous lidar for MA temperature measurements was installed at IS26. Temperature and wind perturbations, considering observed biases and deviations, were added to the operational high-resolution atmospheric model analysis produced by the European Centre for Medium-Range Weather Forecasts. Such uncertainties in horizontal winds and temperature strongly impact propagation conditions, explaining almost 97 per cent of the actual detections, compared to 77 per cent when using the direct output of the NWP model only. Incorporating realistic wind and temperature uncertainties in NWP models can thus significantly improve the understanding of microbarom detections as well as the detection capability of a single station throughout the year.〈/span〉
    Print ISSN: 2051-1965
    Electronic ISSN: 1365-246X
    Topics: Geosciences
    Published by Oxford University Press on behalf of The Deutsche Geophysikalische Gesellschaft (DGG) and the Royal Astronomical Society (RAS).
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  • 8
    Publication Date: 1994-01-01
    Print ISSN: 0937-0633
    Electronic ISSN: 1432-1130
    Topics: Chemistry and Pharmacology
    Published by Springer
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  • 9
    Publication Date: 1995-01-01
    Print ISSN: 0937-0633
    Electronic ISSN: 1432-1130
    Topics: Chemistry and Pharmacology
    Published by Springer
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  • 10
    Publication Date: 1997-10-13
    Print ISSN: 0937-0633
    Electronic ISSN: 1432-1130
    Topics: Chemistry and Pharmacology
    Published by Springer
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