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  • 1
    Publication Date: 2021-03-11
    Description: The elemental and isotopic compositions of noble gases (He, Ne, and Ar) in olivine- and clinopyroxene-hosted fluid inclusions have been measured for rocks at various degrees of evolution and belonging to high-K calcalkaline–shoshonitic and shoshonitic–potassic series in order to cover the entire volcanological history of Vulcano Island (Italy). The major- and trace-element concentrations and the Sr- and Pb-isotope compositions forwhole rockswere integratedwith data obtained fromthe fluid inclusions. 3He/4He in fluid inclusions iswithin the range of 3.30 and 5.94 R/Ra, being lower than the theoretical value for the deepmagmatic source expected for Vulcano Island (6.0–6.2 R/Ra). 3He/4He of themagmatic source is almost constant throughout the volcanic history of Vulcano. Integration of the He- and Sr-isotope systematics leads to the conclusion that a decrease in the Heisotope ratio of the rocks is mainly due to the assimilation of 10–25% of a crustal component similar to the Calabrian basement. 3He/4He shows a negative correlationwith Sr isotopes except for the last-erupted Vulcanello latites (Punta del Roveto),which have anomalously high He isotope ratios. This anomaly has been attributed to a flushing process by fluids coming from the deepest reservoirs, since an input of deep magmatic volatiles with high 3He/4He values increases the He-isotope ratio without changing 87Sr/86Sr. A comparison of the He-isotope ratios between fluid inclusions and fumarolic gases shows that only the basalts of La Sommata and the latites of Vulcanello have comparable values. Taking into account that the latites of Vulcanello relate to one of the most-recent eruptions at Vulcano (in the 17th century), we infer that the most probable magma which actually feeds the fumarolic emissions is a latitic body that ponded at about 3–3.5 km of depth and is flushed by fluids coming from a deeper and basic magma.
    Description: Published
    Description: 272-287
    Description: 1V. Storia e struttura dei sistemi vulcanici
    Description: JCR Journal
    Description: restricted
    Keywords: Helium isotopes, Fluid inclusions ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-05-19
    Description: The Ancestral South Sandwich Arc (ASSA) has a short life-span of c. 20. m.y. (early Oligocene to middle-late Miocene) before slab retreat and subsequent 'resurrection' as the active South Sandwich Island Arc (SSIA). The ASSA is, however, significant because it straddled the eastern margin of the Drake Passage Gateway where it formed a potential barrier to deep ocean water and mantle flow from the Pacific to Atlantic. The ASSA may be divided into three parts, from north to south: the Central Scotia Sea (CSS), the Discovery segment, and the Jane segment. Published age data coupled with new geochemical data (major elements, trace elements, Hf-Nd-Sr-Pb isotopes) from the three ASSA segments place constraints on models for the evolution of the arc and hence gateway development. The CSS segment has two known periods of activity. The older, Oligocene, period produced basic-acidic, mostly calc-alkaline rocks, best explained in terms of subduction initiation volcanism of Andean-type (no slab rollback). The younger, middle-late Miocene period produced basic-acidic, high-K calc-alkaline rocks (lavas and pyroclastic rocks with abundant volcanigenic sediments) which, despite being erupted on oceanic crust, have continental arc characteristics best explained in terms of a large, hot subduction flux most typical of a syn- or post-collision arc setting. Early-middle Miocene volcanism in the Discovery and Jane arc segments is geochemically quite different, being typically tholeiitic and compositionally similar to many lavas from the active South Sandwich Island Arc front. There is indirect evidence for Western Pacific-type (slab rollback) subduction initiation in the southern part of the ASSA and for the back-arc basins (the Jane and Scan Basins) to have been active at the time of arc volcanism. Models for the death of the ASSA in the south following a series of ridge-trench collisions are not positively supported by any geochemical evidence of hot subduction, but cessation of subduction by approach of progressively more buoyant oceanic lithosphere is consistent with both geochemistry and geodynamics. In terms of deep ocean water flow the early stages of spreading at the East Scotia Ridge (starting at 17-15. Ma) may have been important in breaking up the ASSA barrier while the subsequent establishment of a STEP (Subduction-Transform Edge Propagator) fault east of the South Georgia microcontinent (〈. 11. Ma) led to formation of the South Georgia Passage used by the Antarctic Circumpolar Current today. In terms of mantle flow, the subduction zone and arc root likely acted as a barrier to mantle flow in the CSS arc segment such that the ASSA itself became the Pacific-South Atlantic mantle domain boundary. This was not the case in the Discovery and Jane arc segments, however, because the northward flow of the South Atlantic mantle behind the southern part of the ASSA gave an Atlantic provenance to the whole southern ASSA.
    Description: Published
    Repository Name: AquaDocs
    Type: Journal Contribution , Refereed
    Format: pp.298-322
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  • 3
    Electronic Resource
    Electronic Resource
    [s.l.] : Macmillian Magazines Ltd.
    Nature 410 (2001), S. 457-461 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The Earth's convecting upper mantle can be viewed as comprising three main reservoirs, beneath the Pacific, Atlantic and Indian oceans. Because of the uneven global distribution and migration of ridges and subduction zones, the surface area of the Pacific reservoir is at present contracting at ...
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] However, two such ortho -substituted methyl groups (I, R' = R" = CH3) force the oxygen of the carbonyl group out of the plane of the aromatic ring and so suppress carbonyl-ring conjugation. This is shown by the large diminution in the intensity of the ultra-violet absorption in the region 210-300 ...
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1432-0819
    Keywords: Key words Lava dome ; Endogenous ; Basaltic ; Submarine ; Rheology ; Antarctica
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  On King George Island during latest Oligocene/earliest Miocene time, submarine eruptions resulted in the emplacement of a small (ca. 500 m estimated original diameter) basalt lava dome at Low Head. The dome contains a central mass of columnar rock enveloped by fractured basalt and basalt breccia. The breccia is crystalline and is a joint-block deposit (lithic orthobreccia) interpreted as an unusually thick dome carapace breccia cogenetic with the columnar rock. It was formed in situ by a combination of intense dilation, fracturing and shattering caused by natural hydrofracturing during initial dome effusion and subsequent endogenous emplacement of further basalt melt, now preserved as the columnar rock. Muddy matrix with dispersed hyaloclastite and microfossils fills fractures and diffuse patches in part of the fractured basalt and breccia lithofacies. The sparse glass-rich clasts formed by cooling-contraction granulation during interaction between chilled basalt crust and surrounding water. Together with muddy sediment, they were injected into the dome by hydrofracturing, local steam fluidisation and likely explosive bulk interaction. The basalt lava was highly crystallised and degassed prior to extrusion. Together with a low effusion temperature and rapid convective heat loss in a submarine setting, these properties significantly affected the magma rheology (increased the viscosity and shear strength) and influenced the final dome-like form of the extrusion. Conversely, high heat retention was favoured by the degassed state of the magma (minimal undercooling), a thick breccia carapace and viscous shear heating, which helped to sustain magmatic (eruption) temperatures and enhanced the mobility of the flow.
    Type of Medium: Electronic Resource
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  • 6
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    In:  Geological Society Special Publication 246: 359-380.
    Publication Date: 2007-10-08
    Description: The chemistry of mafic volcanic rocks and minor intrusions erupted on continents can be used to define sub-continental asthenospheric and lithospheric mantle sources. Data have been collated from Antarctica and the Falkland Islands (adjacent in Gondwana) in order to identify lithospheric mantle sources beneath the continent. The lithosphere-derived magmas include lamproitic and some lamprophyric rocks and end-members in basaltic suites that are interpreted as mixtures of magmas from lithospheric and asthenospheric sources. The lithosphere-derived mafic rocks from Archaean to Middle Proterozoic cratonic and circumcratonic areas of East Antarctica have time-corrected {varepsilon}Nd values of -20 to -3. This demands isolation of the LREE-enriched sources within pockets of stable sub-cratonic lithosphere for more than 1 Ga, consistent with the lithosphere thickness up to 250 km imaged by seismic tomography. In contrast, lithosphere-derived mafic rocks from Middle Proterozoic to Early Palaeozoic areas of West Antarctica, Victoria Land and the Falkland Islands that formed the Gondwana continental margin, have time-corrected {varepsilon}Nd values of -3.6 to +3.5, implying more recent isolation from asthenosphere. In terms of mantle reservoirs, cratonic and circumcratonic areas trend toward EMI, with EMII possibly being a minor component. In contrast, Gondwana margin areas trend toward EMII, with EMI being, at most, a very minor component.
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  • 7
    Publication Date: 2007-10-08
    Description: An Nd-Sr isotope database, including c. 200 new analyses, is presented for Palaeozoic and Mesozoic metasedimentary successions extending through southeastern Australia, New Zealand, West Antarctica and the Antarctic Peninsula to southern South America. Combining with U-Pb detrital zircon age data, this enables characterization of New Zealand terranes, especially within the Eastern Province, where there is a progression from westernmost terranes of both volcanic/volcaniclastic and accretionary origin with primitive sediment sources, to easternmost terranes with mature continental sediment inputs. In southern South America, West Antarctica and the Antarctica Peninsula, similar accretionary complexes have Nd model ages principally reflecting mixing of sedimentary material from multiple sources, both mature and juvenile. A mature Gondwana continental provenance dominates in sedimentary basins inboard of the active margin, especially in the Palaeozoic (Western Province, New Zealand, interior West Antarctica and NW Argentina), and contributes significantly to pre-Mesozoic sedimentary rocks of Patagonia east of the Andes. Along the Gondwanaland margin, Nd systematics for younger (late Palaeozoic to early Mesozoic) accretionary complex metasediments reflect younger source inputs, notably in the Scotia metamorphic complex. Many of the accretionary complex deposits must involve significant crustal reworking. There is no apparent South American equivalent of the primitive provenance of the westernmost accretionary terranes of New Zealand.
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  • 8
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    In:  Geological Society Special Publication 219: 285-313.
    Publication Date: 2003-01-01
    Description: The South Sandwich Islands are one of the world's classic examples of an intraoceanic arc. Formed on recently generated back-arc crust, they represent the earliest stages of formation of arc crust, and are an excellent laboratory for investigating variations in magma chemistry resulting from mantle processes, and generation of silicic magmas in a dominantly basaltic environment. Two volcanoes are examined. Southern Thule in the south of the arc is a complex volcanic edifice with three calderas and compositions that range from mafic to silicic and tholeiitic to calc-alkaline. It is compared to the Candlemas-Vindication edifice in the north of the arc, which is low-K tholeiitic and strongly bimodal from mafic to silicic. Critically, Southern Thule lies along a cross-arc, wide-angle seismic section that reveals the velocity structure of the underlying arc crust. Trace element variations are used to argue that the variations in both mantle depletion and input of a subducted sediment component produced the diverse low-K tholeiite, tholeiite and calc-alkaline series. Primitive, mantle-derived melts fractionally crystallized by c. 36% to produce the most Mg-rich erupted basalts and a high-velocity cumulitic crustal keel. Plagioclase cumulation produced abundant high-Al basalts (especially in the tholeiitic series), and strongly influenced Sr abundances in the magmas. However, examination of volumetric and geochemical arguments indicates that the silicic rocks do not result from fractional crystallization, and are melts of amphibolitic arc crust instead.
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  • 9
    Publication Date: 2003-01-01
    Description: The East Scotia Ridge, situated in the South Atlantic, is the back-arc spreading centre to the intra-oceanic South Sandwich arc. Samples from the ridge show a wide diversity in erupted magma compositions. Segment E2, in the northern part of the ridge, has an axial topographic high, which contrasts with the rift-like topography common to most of the ridge. Lava compositions in the segment have been modelled by mixing of magmas derived from normal mid-ocean ridge basalt (N-MORB)-like mantle, a mantle plume component similar in composition to that sampled by Bouvet Island and mantle modified by addition of components from the subducting slab. The Bouvet'-like plume signature has higher 87Sr/86Sr, 206Pb/204Pb, Nb/Yb, and lower 143Nd/144Nd and 4He/3He, than the local upper mantle. It can be traced geochemically from the Bouvet Island hot spot to segment E2, via the South American-Antarctic Ridge, which connects the Bouvet triple junction to the South Sandwich subduction system. Four samples dredged from segment E2 have 4He/3He ratios of 85 000-90 200 (8.5-8.0 R/RA, where) R/RA is the 4He/3He ratio normalized to air) and three wax core samples taken from the segment axis have values of 104 300, 101 560 and 176 620 (6.9, 7.1 and 4.1 R/RA). These latter data are similar to values from the South American-Antarctic Ridge which have no discernable plume input. Whilst the dredge samples have a measurably lower 4He/3He ratio than the South American-Antarctic Ridge and samples from the segment axis, these He isotope data contrast with a dominant plume signature recorded by other petrogenetic tracers. This is interpreted to be due to re-melting of an entrained plume component, with an inherent low He concentration, incorporated into the E2 mantle. Helium depletion from the plume component can be seen to be a consequence of mantle processing and does not imply shallow-level degassing prior to entrainment within the upper-mantle-melting zone. As a consequence, He is characterized in the back-arc by values more similar to the upper mantle, whereas lithophile tracers are more influenced by the plume component.
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  • 10
    Publication Date: 2015-09-23
    Description: The Matachewan Large Igneous Province (LIP) is interpreted to have formed during the early stages of mantle plume-induced continental break-up in the early Proterozoic. When the Matachewan LIP is reconstructed to its original configuration with units from the Superior Craton and other formerly adjacent blocks (Karelia, Kola, Wyoming and Hearne), the dyke swarms, layered intrusions and flood basalts, emplaced over the lifetime of the province, form one of the most extensive magmatic provinces recognized in the geological record. New geochemical data allow, for the first time, the Matachewan LIP to be considered as a single, coherent entity and show that Matachewan LIP rocks share a common tholeiitic composition and trace element geochemistry, characterized by enrichment in the most incompatible elements and depletion in the less incompatible elements. This signature, ubiquitous in early Proterozoic continental magmatic rocks, may indicate that the Matachewan LIP formed through contamination of the primary magmas with lithospheric material or that the early Proterozoic mantle had a fundamentally different composition from the modern mantle. In addition to the radiating geometry of the dyke swarms, a plume origin for the Matachewan LIP is consistent with the geochemistry of some of the suites; these suites are used to constrain a source mantle potential temperature of c. 1500–1550°C. Comparison of these mantle potential temperatures with estimated temperatures for the early Proterozoic upper mantle indicates that they are consistent with a hot mantle plume source for the magmatism. Geochemical data from coeval intrusions suggest that the plume head was compositionally heterogeneous and sampled material from both depleted and enriched mantle. As has been documented with less ancient but similarly vast LIPs, the emplacement of the Matachewan LIP probably had a significant impact on the early Proterozoic global environment. Compilation of the best age estimates for various suites shows that the emplacement of the Matachewan LIP occurred synchronously with the Great Oxidation Event. We explore the potential for the eruption of this LIP and the emission of its associated volcanic gases to have been a driver of the irreversible oxygenation of the Earth.
    Print ISSN: 0022-3530
    Electronic ISSN: 1460-2415
    Topics: Geosciences
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