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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 91 (2002), S. 3912-3917 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have demonstrated the patterned heteroepitaxial processing (PHP) approach for the removal of threading dislocations (TDs) from ZnSe and ZnS0.02Se0.98 on GaAs (001). PHP involves the growth of a continuous heteroepitaxial layer followed by postgrowth patterning and annealing. We found that the basic mechanism of TD removal by PHP is thermally activated dislocation motion in the presence of sidewalls. By studying the temperature dependence we showed that the activation energy for the annealing process (∼0.7 eV in ZnSe on GaAs) is consistent with dislocation motion by glide. We showed that there is a minimum mesa thickness required for the complete removal of TDs by PHP (∼3000 Å for 70 μm×70 μm mesas of ZnSe on GaAs). This is because the lateral forces acting on TDs are proportional to the mesa thickness. We also conducted a preliminary study of the mismatch dependence of PHP. Our results suggest that PHP removes TDs more effectively in the higher lattice mismatch system ZnSe/GaAs (001) than in the lower lattice mismatch system ZnS0.02Se0.98/GaAs (001). This is expected based on the mismatch dependence of the line tension forces in the misfit segments of dislocations. © 2002 American Institute of Physics.
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 87 (2000), S. 8080-8087 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A time-dependent finite-difference beam propagation method is presented to analyze quantum interference transistor (QUIT) structures, employing the Aharonov–Bohm effect, in both steady state and transient conditions. Current–voltage characteristics of two ring structures having 0.2 and 0.05 μm channel lengths, respectively, are presented. Additionally, the wave functions are calculated, and reflections are observed in both the ON and OFF states of the device. Cutoff frequency fT values of 3 and 8.5 THz, respectively, are calculated from the switching response to a gate pulse of 200 fs, for the 0.2 μm device, and to a pulse of 50 fs, for the 0.05 μm device. Results indicate that reflections at the drain may degrade frequency performance of these devices, which is not evident from earlier analytical studies. These structures are further explored to investigate the effects of imperfections introduced in fabricating the quantum wire channels. We compare two QUITs, one realized by a 1 nm resolution lithography process (representing an advanced fabrication technique) and the other realized by a 10 nm resolution (representing current state-of-the-art lithography). We also present an asymmetric 10 nm resolution structure, to represent the case when errors in fabrication significantly alter the QUIT topology. This simulation shows strong dependence of the electron transmission probability on the channel topology and roughness determined by the lithographic resolution. © 2000 American Institute of Physics.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 81 (1997), S. 497-501 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Variable angle spectroscopic ellipsometry (VASE) technique is used to measure the optical constants of InGaAs/GaAs multiple quantum well (MQW) structures for the purpose of designing tunable optical modulators. The VASE measurements also include field-induced changes in index of refraction and absorption. These measured changes in MQWs are in agreement with theoretical computations. In addition, the design and simulated performance of an InGaAs/GaAs MQWs Fabry–Perot modulator using the VASE data is presented. © 1997 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 1098-1100 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Zinc selenide epitaxial layers have been grown by ultraviolet-assisted organometallic vapor phase epitaxy (OMVPE) with cadmium and chlorine codoping, using the sources DMSe, DMZn, DMCd, and HCl. Growth was carried out at 400 °C with ultraviolet irradiation at an intensity of 4 or 7.5 mW/cm2. Samples codoped with cadmium showed increased incorporation of chlorine donors relative to control samples having no cadmium codoping. This effect was more pronounced at the lower ultraviolet intensity. The growth rate for the doped films decreased with increasing mole fraction of hydrogen chloride. By the use of cadmium codoping, we have achieved the highest electron concentrations yet reported for hydrogen chloride doping of OMVPE-grown ZnSe. The best results obtained in this study were an electron concentration of 2.4×1018 cm−3 and a resistivity of 0.0141 Ω cm (300 K values). We have proposed a model based on the compensation of tetrahedral misfit to explain these results. © 1995 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 66 (1995), S. 1596-1598 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Gain coefficient of excitonic transitions is calculated for unstrained as well as strained ZnCdSe/ZnMgSSe multiple quantum well (MQW) lasers as a function of operating wavelength and injection current. Unlike the III–V strained layer quantum well lasers, the gain coefficient due to excitonic transitions is significantly higher in II–VI systems as the exciton binding energy is more than 5 times larger. This results in a primary role for excitons in lasing which has been verified experimentally. Strain induced changes in energy band gaps and effective masses of light and heavy holes are included in the gain and threshold current density calculations, which are in agreement with experimental data available for compressive strained layers grown on GaAs substrates. Significantly low threshold current density of about 180 A/cm2 are predicted for the tensile strained ZnCdSe–ZnMgSSe and ZnCdSe–ZnSeTe quantum well lasers using InP substrates. © 1995 American Institute of Physics.
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 63 (1993), S. 296-298 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Tunable Fabry–Perot modulators, consisting of strained InGaAs-GaAs multiple quantum well (MQW) layers, have been shown to yield a contrast over 1200:1. Tuning is achieved by varying the index of refraction of the MQW layers forming the cavity using a quantum confined Stark effect. The mirrors are realized by AlAs-GaAs quarter wave λ/4 dielectric stacks having 12 and 15.5 periods, respectively. The device has the potential of achieving even higher tunable contrast ratios when the number of periods of the λ/4 mirrors are increased. A contrast ratio of 6000:1 has been achieved for a nontunable structure. Measured data on optical transmission and contrast ratio are presented for various wavelengths as a function of applied bias. Results of simulation of transmitted output are also discussed.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 1693-1695 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the influence of impurities on the dislocation behavior in heteroepitaxial layers of ZnSe on GaAs, grown by photoassisted organometallic vapor phase epitaxy. In undoped ZnSe layers, the dislocation densities are similar to those obtained by [S. Akram, H. Eshani, and I. B. Bhat, J. Cryst. Growth 124, 628 (1992)] whose data show that there is an inverse relationship between layer thickness and dislocation density. Incorporation of the electronically active impurity Cl increases the dislocation densities relative to undoped layers of the same thickness. Also, there is a correlation between the normalized dislocation density and the concentration of incorporated Cl. The isoelectronic impurity Cd has a similar effect on the dislocation density. Incorporation of Cd to a concentration of ∼1020/cm3 increases the dislocation density by a factor of about 3 compared to undoped layers of equal thickness. We also observed that doping of both Cd and Cl together resulted in low dislocation densities similar to the undoped case. Based on our results, we believe that the controlling factor for this phenomenon is the absolute value of the tetrahedral misfit for the impurity, rather than its sign, or the electronic activity of the impurity, or the sublattice on which the impurity resides. We propose an "impurity hardening'' model to explain these results. According to this model the glide of dislocations is inhibited by the addition of impurities due to the local strain fields around the substitutional sites. The higher dislocation densities observed here with doping are an indirect result of impurity hardening. However, for single crystals or pseudomorphic heteroepitaxial layers, impurity hardening can inhibit the introduction of dislocations. © 1996 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 2524-2526 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report the effectiveness of patterned heteroepitaxial processing (PHP) in removing threading dislocations (TDs) from ZnSe epitaxial layers grown on GaAs substrates by metalorganic vapor phase epitaxy. The PHP approach used here involves postgrowth patterning of continuous epitaxial layers followed by annealing. In this study, each as-grown ZnSe/GaAs sample was first cut into pieces forming four types of samples, namely: (1) as grown, (2) postgrowth annealed, (3) postgrowth patterned, and (4) PHP prepared (patterned and annealed). The epitaxial layers with thicknesses of 2000–6000 Å were patterned to create 500–6000-Å-high and 3–70-μm-wide square mesas that were separated by 20 μm trenches. TD densities were determined by the etch pit density (EPD) technique and comparisons were made between the four types of samples. The first three types of samples exhibited EPDs of approximately 107 cm−2, which indicate that neither patterning alone nor annealing alone was effective at reducing TDs. In contrast, PHP resulted in a complete removal of TDs from 70 μm×70 μm square layers with thicknesses of 〉3000 Å. This corresponds to an EPD less than 2.0×104 cm−2, and at least a 500-fold reduction compared to as-grown layers; in fact, this value is even lower than that of the GaAs substrate (EPD=105 cm−2). Thus TDs can be removed in PHP by glide to the sidewalls, as promoted by the presence of image forces. © 2000 American Institute of Physics.
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  • 9
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A three-dimensional coupled-well excitonic model is presented to explain the observed shift in the photoluminescence excitation spectrum, emission peak from Mn2+ ions, and five-to-six orders reduction of radiative lifetime in ZnS:Mn2+(35 Å) doped nanocrystals. For pseudomorphic cladded nanocrystals such as ZnCdSe–ZnMgSSe, a modified excitonic model predicts enhancements in the absorption coefficient (α∼160 000 cm−1) and electric field-dependent index of refraction change (Δn/n∼0.1–0.2), and a significant reduction of radiative lifetime τr∼14.5 fs. Optical gain and threshold current density (Jth) are computed for ZnCdSe–ZnMgSSe and InGaN–AlGaN quantum dot lasers. In the case of InGaN–AlGaN quantum dot lasers, the effect of dislocation-induced traps, enhancement of optical gain due to excitonic transitions, and dot size are considered in the computation of Jth. It is shown that InGaN dots with larger cross sections (∼200×250 Å, such as self-organized dots) and consisting of a trap density of 2.9×1017 cm−3 yield Jth of 4500 A/cm2 in comparison to 136 A/cm2 for dots of size 35×35×35 Å. This explains the observation of higher current density in InGaN quantum well lasers having self-organized dots. © 1999 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 51 (1995), S. 498-503 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Recently, a general technique for the measurement for the threading dislocation densities in epitaxic semiconductors by high-resolution X-ray diffraction was reported [Ayers (1994). J. Cryst. Growth, 135, 71–77]. Here, this method has been extended to the case of a Barrels five-crystal diffactometer by making use of known instrumental effects for this diffractometer. The usefulness of the method has been demonstrated by application of the technique to epitaxic ZnSe grown on GaAs (001) by photo-assisted metalorganic vapor-phase epitaxy. It is shown that in this case the threading dislocation density of the epitaxic layer can be determined quantitatively. Evidence for the introduction of dislocations in the underlying GaAs substrate is also presented.
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