ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The spirophosphorane 4 underwent reaction with a series of benzene-sulphenic esters 3 to give the corresponding isolable alkoxyphosphoranes. The reactivities of benzenesulphenic esters 3 in this reaction were seen to be dependent on steric hindrance of the R groups. The yields of alkoxyphosphoranes were influenced by the reaction temperature. The probable mechanism was suggested in terms of experimental observations.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520040103
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