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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 70 (1966), S. 2763-2767 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Geophysical Research Letters 39 (2012): L15501, doi:10.1029/2012GL052222.
    Description: Starting in Late Pleistocene time (~19 ka), sea level rise inundated coastal zones worldwide. On some parts of the present-day circum-Arctic continental shelf, this led to flooding and thawing of formerly subaerial permafrost and probable dissociation of associated gas hydrates. Relict permafrost has never been systematically mapped along the 700-km-long U.S. Beaufort Sea continental shelf and is often assumed to extend to ~120 m water depth, the approximate amount of sea level rise since the Late Pleistocene. Here, 5,000 km of multichannel seismic (MCS) data acquired between 1977 and 1992 were examined for high-velocity (〉2.3 km s−1) refractions consistent with ice-bearing, coarse-grained sediments. Permafrost refractions were identified along 〈5% of the tracklines at depths of ~5 to 470 m below the seafloor. The resulting map reveals the minimum extent of subsea ice-bearing permafrost, which does not extend seaward of 30 km offshore or beyond the 20 m isobath.
    Description: This research was sponsored by DOE-USGS Interagency Agreement DE-FE0002911. L.B. was supported by a DOE NETL/NRC Methane Hydrate Fellowship under DE-FC26-05NT42248.
    Keywords: Beaufort Sea ; Climate change ; Methane hydrates ; Refraction ; Sea level ; Subsea permafrost
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 3
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 25 (2008): 952-959, doi:10.1016/j.marpetgeo.2008.01.015.
    Description: To determine the impact of seeps and focused flow on the occurrence of shallow gas hydrates, several seafloor mounds in the Atwater Valley lease area of the Gulf of Mexico were surveyed with a wide range of seismic frequencies. Seismic data were acquired with a deep-towed, Helmholz resonator source (220–820 Hz); a high-resolution, Generator-Injector air-gun (30–300 Hz); and an industrial air-gun array (10–130 Hz). Each showed a significantly different response in this weakly reflective, highly faulted area. Seismic modeling and observations of reversed-polarity reflections and small scale diffractions are consistent with a model of methane transport dominated regionally by diffusion but punctuated by intense upward advection responsible for the bathymetric mounds, as well as likely advection along pervasive filamentous fractures away from the mounds.
    Description: This work was funded through ONR program element 61153N, and U.S. Department of Energy Grant DE-A126-97FT3423.
    Keywords: Methane hydrate ; Seafloor seep
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 4
    Publication Date: 2022-05-25
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 25 (2008): 969-976, doi:10.1016/j.marpetgeo.2008.01.020.
    Description: In the northern Gulf of Mexico, a series of seafloor mounds lie along the floor of the Mississippi Canyon in Atwater Valley lease blocks 13 and 14. The mounds, one of which was drilled by the Chevron Joint Industry Project on Methane Hydrates in 2005, are interpreted to be vent-related features that may contain significant accumulations of gas hydrate adjacent to gas and fluid migration pathways. The mounds are located not, vert, similar150 km south of Louisiana at not, vert, similar1300 m water depth. New side-scan sonar data, multibeam bathymetry, and near-bottom photography along a 4 km northwest–southeast transect crossing two of the mounds (labeled D and F) reveal the mounds' detailed morphology and surficial characteristics. Mound D, not, vert, similar250 m in diameter and 7–10 m in height, has exposures of authigenic carbonates and appears to result from a seafloor vent of slow-to-moderate flux. Mound F, which is not, vert, similar400 m in diameter and 10–15 m high, is covered on its southwest flank by extruded mud flows, a characteristic associated with moderate-to-rapid flux. Chemosynthetic communities visible on the bottom photographs are restricted to bacterial mats on both mounds and mussels at Mound D. No indications of surficial gas hydrates are evident on the bottom photograph
    Description: Partial support for the research cruises that collected the data for this study was provided by the Department of Energy, National Energy Technology Lab.
    Keywords: Gas hydrate ; Seafloor mounds ; Side-scan sonar ; Multibeam bathymetry ; Near-bottom photography ; Chemosynthetic communities
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 17 (2016): 4333–4353, doi:10.1002/2016GC006582.
    Description: Borehole logging data from legacy wells directly constrain the contemporary distribution of subsea permafrost in the sedimentary section at discrete locations on the U.S. Beaufort Margin and complement recent regional analyses of exploration seismic data to delineate the permafrost's offshore extent. Most usable borehole data were acquired on a ∼500 km stretch of the margin and within 30 km of the contemporary coastline from north of Lake Teshekpuk to nearly the U.S.-Canada border. Relying primarily on deep resistivity logs that should be largely unaffected by drilling fluids and hole conditions, the analysis reveals the persistence of several hundred vertical meters of ice-bonded permafrost in nearshore wells near Prudhoe Bay and Foggy Island Bay, with less permafrost detected to the east and west. Permafrost is inferred beneath many barrier islands and in some nearshore and lagoonal (back-barrier) wells. The analysis of borehole logs confirms the offshore pattern of ice-bearing subsea permafrost distribution determined based on regional seismic analyses and reveals that ice content generally diminishes with distance from the coastline. Lacking better well distribution, it is not possible to determine the absolute seaward extent of ice-bearing permafrost, nor the distribution of permafrost beneath the present-day continental shelf at the end of the Pleistocene. However, the recovery of gas hydrate from an outer shelf well (Belcher) and previous delineation of a log signature possibly indicating gas hydrate in an inner shelf well (Hammerhead 2) imply that permafrost may once have extended across much of the shelf offshore Camden Bay.
    Description: 2017-05-04
    Keywords: Permafrost ; Arctic Ocean ; Climate change ; Borehole logging ; Gas hydrates
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-05-26
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Marine and Petroleum Geology 25 (2008): 906-918, doi:10.1016/j.marpetgeo.2008.01.012.
    Description: The Keathley Canyon sites drilled in 2005 by the Chevron Joint Industry Project are located along the southeastern edge of an intraslope minibasin (Casey basin) in the northern Gulf of Mexico at 1335 m water depth. Around the drill sites, a grid of 2D high-resolution multichannel seismic data designed to image depths down to at least 1000 m sub-bottom reveals 7 unconformities and disconformities that, with the seafloor, bound 7 identifiable seismic stratigraphic units. A major disconformity in the middle of the units stands out for its angular baselapping geometry. From these data, three episodes of sedimentary deposition and deformation are inferred. The oldest episode consists of fine-grained muds deposited during a period of relative stability in the basin (units e, f, and g). Both the BSR and inferred gas hydrate occur within these older units. The gas hydrate occurs in near-vertical fractures. A second episode (units c and d) involved large vertical displacements associated with infilling and ponding of sediment. This second interval corresponds to deposition of intercalated fine and coarse-grained material that was recovered in the drill hole that penetrated the thin edges of the regionally much thicker units. The final episode of deposition (units a and b) occurred during more subdued vertical motions. Hemipelagic drape (unit a) characterizes the modern seafloor. The present-day Casey basin is mostly filled. Its sill is part of a subsiding graben structure that is only 10–20 m shallower than the deepest point in the basin, indicating that gravity-driven transport would mostly bypass the basin. Contemporary faulting along the basin margins has selectively reactivated an older group of faults. The intercalated sand and mud deposits of units c and d are tentatively correlated with Late Pleistocene deposition derived from the western shelf-edge delta/depocenter of the Mississippi River, which was probably most active from 320 ka to 70 ka [Winker, C.D., Booth, J., 2000. Sedimentary dynamics of the salt-dominated continental slope, Gulf of Mexico: integration of observations from the seafloor, near-surface, and deep subsurface. In: Proceedings of the GCSSEPM Foundation 20th Annual Research Conference, Deep-water Reservoirs of the World, pp. 1059–1086]. The presence of sand within the gas hydrate stability zone (in units c and d) is not sufficient to concentrate gas hydrate even though dispersed gas hydrate occurs deeper in the fractured mud/clay-rich sections of units e and f.
    Description: Partial support for the field and interpretive aspects of this project were provided by the Department of Energy, National Energy Technology Lab (NETL).
    Keywords: Gulf of Mexico ; Gas hydrate ; Methane hydrate ; Geologic framework ; Joint industry projects ; JIP
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2014. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 119 (2014): 8594–8609, doi:10.1002/2014JB011290.
    Description: The most climate-sensitive methane hydrate deposits occur on upper continental slopes at depths close to the minimum pressure and maximum temperature for gas hydrate stability. At these water depths, small perturbations in intermediate ocean water temperatures can lead to gas hydrate dissociation. The Arctic Ocean has experienced more dramatic warming than lower latitudes, but observational data have not been used to study the interplay between upper slope gas hydrates and warming ocean waters. Here we use (a) legacy seismic data that constrain upper slope gas hydrate distributions on the U.S. Beaufort Sea margin, (b) Alaskan North Slope borehole data and offshore thermal gradients determined from gas hydrate stability zone thickness to infer regional heat flow, and (c) 1088 direct measurements to characterize multidecadal intermediate ocean warming in the U.S. Beaufort Sea. Combining these data with a three-dimensional thermal model shows that the observed gas hydrate stability zone is too deep by 100 to 250 m. The disparity can be partially attributed to several processes, but the most important is the reequilibration (thinning) of gas hydrates in response to significant (~0.5°C at 2σ certainty) warming of intermediate ocean temperatures over 39 years in a depth range that brackets the upper slope extent of the gas hydrate stability zone. Even in the absence of additional ocean warming, 0.44 to 2.2 Gt of methane could be released from reequilibrating gas hydrates into the sediments underlying an area of ~5–7.5 × 103 km2 on the U.S. Beaufort Sea upper slope during the next century.
    Description: This work was supported by the U.S. Department of Energy (DOE), grant DE-FE0010180 to SMU and a USGS-DOE interagency agreement DE-FE0005806.
    Description: 2015-06-09
    Keywords: Gas hydrate ; Heat flow ; Seismic reflection ; Ocean temperature ; Modeling ; Beaufort Sea
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 8
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 17 (2016): 4354–4365, doi:10.1002/2016GC006584.
    Description: Subsea ice-bearing permafrost (IBPF) and associated gas hydrate in the Arctic have been subject to a warming climate and saline intrusion since the last transgression at the end of the Pleistocene. The consequent degradation of IBPF is potentially associated with significant degassing of dissociating gas hydrate deposits. Previous studies interpreted the distribution of subsea permafrost on the U.S. Beaufort continental shelf based on geographically sparse data sets and modeling of expected thermal history. The most cited work projects subsea permafrost to the shelf edge (∼100 m isobath). This study uses a compilation of stacking velocity analyses from ∼100,000 line-km of industry-collected multichannel seismic reflection data acquired over 57,000 km2 of the U.S. Beaufort shelf to delineate continuous subsea IBPF. Gridded average velocities of the uppermost 750 ms two-way travel time range from 1475 to 3110 m s−1. The monotonic, cross-shore pattern in velocity distribution suggests that the seaward extent of continuous IBPF is within 37 km of the modern shoreline at water depths 〈 25 m. These interpretations corroborate recent Beaufort seismic refraction studies and provide the best, margin-scale evidence that continuous subsea IBPF does not currently extend to the northern limits of the continental shelf.
    Description: DOE NETL/NRC Methane Hydrate Fellowship Grant Number: DE-FC26-05NT42248; USGS–DOE Interagency Agreements Grant Number: DE-FE000291 and 0023495
    Description: 2017-05-04
    Keywords: Subsea permafrost ; Gas hydrates ; Multichannel seismic data ; Arctic Ocean
    Repository Name: Woods Hole Open Access Server
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  • 9
    Publication Date: 2022-05-26
    Description: Author Posting. © The Author(s), 2007. This is the author's version of the work. It is posted here by permission of Elsevier B.V. for personal use, not for redistribution. The definitive version was published in Journal of Geochemical Exploration 95 (2007): 1-15, doi:10.1016/j.gexplo.2007.05.011.
    Description: Authigenic carbonates were sampled in piston cores collected from both the Tunica Mound and the Mississippi Canyon area on the continental slope of the northern Gulf of Mexico during a Marion Dufresne cruise in July 2002. The carbonates are present as hardgrounds, porous crusts, concretions or nodules and shell fragments with or without carbonate cements. Carbonates occurred at gas venting sites which are likely to overlie gas hydrates bearing sediments. Electron microprobe, X-ray diffraction (XRD) and thinsection investigations show that these carbonates are high-Mg calcite (6 - 21 mol % MgCO3), with significant presence of framboidal pyrite. All carbonates are depleted in 13C (δ13C = -61.9 to -31.5 ‰ PDB) indicating that the carbon is derived mainly from anaerobic methane oxidation (AMO). Age estimates based on 14C dating of shell fragments and on regional sedimentation rates indicate that these authigenic carbonates formed within the last 1,000 yr in the Mississippi Canyon and within 5,500 yr at the Tunica Mound. The oxygen isotopic composition of carbonates ranges from +3.4 to +5.9 ‰ PDB. Oxygen isotopic compositions and Mg2+ contents of carbonates, and present in-situ temperatures of bottom seawater/sediments, show that some of these carbonates, especially from a core associated with underlying massive gas hydrates precipitated in or near equilibrium with bottom-water. On the other hand, those carbonates more enriched in 18O are interpreted to have precipitated from 18O-rich fluids which are thought to have been derived from the dissociation of gas hydrates. The dissociation of gas hydrates in the northern Gulf of Mexico within the last 5,500 yr may be caused by nearby salt movement and related brines.
    Description: Financial support for this work was provided by the Grant-in-Aid from the Ministry of Education and Science and the Research Grant from JAPEX.
    Keywords: Methane-derived authigenic carbonates ; Gulf of Mexico ; High Mg-calcite ; Carbon and oxygen isotope ; Age of authigenic carbonates ; Dissociation of gas hydrates
    Repository Name: Woods Hole Open Access Server
    Type: Preprint
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  • 10
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