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  • 11
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 4 (1971), S. 400-400 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 26 (1970), S. 456-457 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Minute but relatively rapid changes of crystal orientation can lead to significant errors in integrated intensity measurements.
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  • 13
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 34 (1978), S. 1028-1029 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: It is shown that a small single crystal may resonate at a wide range of X- and γ-ray frequencies. Such a resonator should produce roughly 1011 times greater radiative flux density per photon than previous designs.
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  • 14
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 4 (1971), S. 172-172 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: By looking for white-radiation streaks rather than reflexions due to characteristic radiation, the systematic search for scattering vectors is reduced from a three- to a two-parameter problem.
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  • 15
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 4 (1971), S. 331-332 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: A diffractometer-mounted device for the controlled α-irradiation of the single crystals is described.
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  • 16
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 9 (1976), S. 511-511 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 33 (1977), S. 438-440 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Integrated intensity measurements depend on the wavelength range of integration. In conventional X- ray measurement procedures this range decreases with increasing diffraction angle, which results in a systematic intensity error for which normally no correction is applied. This paper presents an experimental investigation of this error for standard integration scans. A correction formula is derived and tested, and it is shown that failure to take account of this error has led to spuriously high temperature factors in most X-ray structure analyses.
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  • 18
    Electronic Resource
    Electronic Resource
    [S.l.] : International Union of Crystallography (IUCr)
    Acta crystallographica 33 (1977), S. 987-992 
    ISSN: 1600-5724
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: It is possible to obtain essentially monochromatic spot profiles with a single-crystal diffractometer by using the specimen crystal as a dispersive element, and by carrying out an ω/θ integration scan with restricted detector slits. An expression for the detector slit width is derived and the technique is tested experimentally. It appears that there is little difficulty in monochromating to ± 1% of the nominal X-ray wavelength as a routine procedure. It is also quite straightforward to work with the Kα1 line alone for medium and high-angle reflexions. The range of wavelengths detected can be made independent of diffraction angle; integrated intensity errors due to variable spectral response can therefore be effectively eliminated. This technique facilitates a higher and more constant degree of X-ray monochromation than the pyrolytic-graphite monochromator or the solid-state detector.
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 1 (1971), S. 311-318 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract p-toluidinium bifluoride crystallizes in the orthorhombic space groupPbca, witha = 7·161,b = 18·405,c = 11·824 Å andZ= 8. The structure was solved by direct methods from X-ray counter data measured with CuKα. radiation, and a finalR index of 0·052 was obtained for the 642 observed terms of the 1480 possible. Thep-toluidine molecule is fully protonated and the methyl group is either disordered, librating extensively or freely rotating. In the HF2 − ion the H atom is apparently centrally situated between the two fluorine atoms, and is obviously very delocalized; the F-H-F distance is 2·276 ± 0·005 Å. The structure consists of alternate layers ofp-toluidinium and hydrogenbifluoride ions with the latter hydrogen-bonded to the amine groupings.
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 4 (1974), S. 141-148 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Crystals of N,O-diacetyl-5-p-chloranilino-4-hydroxypenta-2,4-dienal, the degradation product from a Stenhouse salt, belong to the monoclinic space groupP21/c witha = 10.845,b = 17.607,c = 8.056 Å, β = 95.87 ° andZ = 4. The structure was solved by the heavy-atom method from intensity data measured out to 1.14 Å−1 with CuKα radiation. Hydrogen atoms were not located. A finalR of 0.098 for the 549 observed terms was attained. The molecule is in thetrans-trans conformation, and the non-hydrogen atoms in the pentadienal chain and N-acetyl group are almost co-planar. Thep-chloraniline and O-acetyl groups lie on the same side of the pentadienal skeleton, and their respective planes are approximately parallel and at right angles to the plane of the chain. The molecules in the crystal structure are held together by van der Waals' interactions.
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