ALBERT

Description: The present investigation is concerned with the mutual influence of creep and fatigue in the case of Ti-6211, which represents a new weldable, stress-corrosion resistant alloy. Attention is given to the effect of creep on fatigue, the effect of fatigue on creep, and microstructural studies. It is found that prior creep in the amounts investigated, from 0.2 percent to 2.7 percent, is beneficial to low-cycle fatigue life. Hold time at peak strain is found to be beneficial to low-cycle fatigue life. Hold time at constant stress has no effect on low-cycle fatigue when specimens are cycled only once between hold times; but increasing fatigue loading for 50 or more cycles between hold times can prolong the fatigue life. There is an acceleration of creep by cyclic loading when comparison of cyclic and static creep is based on mean stress.

Description: A numerical simulation code for investigating equatorial Spread F in the collisional Rayleigh-Taylor regime is utilized to follow the evolution of artificial plasma density depletions injected into the bottomside nighttime equatorial F region. The 70 km diameter hole rapidly rises and steepens, forming plasma density enhancements at altitudes below the rising hole. The distribution of enhancements and depletions is similar to natural equatorial Spread F phenomena, except it occurs on a much faster time scale. These predictions warrant carrying out artificial injection experiments in the nighttime equatorial F region.

Description: The nonlinear progressive wave equation (NPE) model was developed by the Naval Ocean Research and Development Activity during 1982 to 1987 to study nonlinear effects in long range oceanic propagation of finite amplitude acoustic waves, including weak shocks. The NPE model was applied to propagation of a generic shock wave (initial condition provided by Sandia Division 1533) in a few illustrative environments. The following consequences of nonlinearity are seen by comparing linear and nonlinear NPE results: (1) a decrease in shock strength versus range (a well-known result of entropy increases at the shock front); (2) an increase in the convergence zone range; and (3) a vertical meandering of the energy path about the corresponding linear ray path. Items (2) and (3) are manifestations of self-refraction.

Description: Long-term atmospheric NOx/CO enhancement ratios in megacities provide evaluations of emission inventories. A fuel-based emission inventory approach that diverges from conventional bottom-up inventory methods explains 1970–2015 trends in NOx/CO enhancement ratios in Los Angeles. Combining this comparison with similar measurements in other U.S. cities demonstrates that motor vehicle emissions controls were largely responsible for U.S. urban NOx/CO trends in the past half century. Differing NOx/CO enhancement ratio trends in U.S. and European cities over the past 25 years highlights alternative strategies for mitigating transportation emissions, reflecting Europe's increased use of light-duty diesel vehicles and correspondingly slower decreases in NOx emissions compared to the U.S. A global inventory widely used by global chemistry models fails to capture these long-term trends and regional differences in U.S. and Europe megacity NOx/CO enhancement ratios, possibly contributing to these models' inability to accurately reproduce observed long-term changes in tropospheric ozone.

Description: Accurate knowledge of tropospheric ozone is important for understanding its current and future effects on human health, air quality, and climate. However, global chemistry- climate models generally have problems reproducing tropospheric ozone concentrations, seasonal cycles and interannual trends. Successful tropospheric ozone simulations require high quality information on the emissions of ozone precursors, including nitrogen oxides (NOx), carbon monoxide (CO) and volatile organic compounds (VOCs). We analyzed CO and NOx measurements from four megacities (Los Angeles, New York City, London, and Paris). It has been shown that CO and VOC emissions are highly correlated in urban areas. However, CO is more extensively measured than VOCs. Therefore, we compared the long-term evolution of the measured NOx/CO enhancement ratio in each city to the ratio of the emissions of these two pollutants reported by the MACCity global emissions inventory at the inventory grid points nearest the city. The longest available measurement record (~50 years) is from Los Angeles, where the measured NOx/CO ratios are consistently smaller than the emission ratio in the MACCity inventory and the slope of the long-term trend in measured NOx/CO ratios is of significantly larger magnitude than for MACCity. The other three cities do not have as long of a data record, but the evolution of their NOx/CO ratios also implies that the MACCity NOx/CO emissions trends are not steep enough. However, the agreement between the measured and inventory ratios is better for the shorter time period where measurements are available in these three cities. Comparisons of MACCity with fuel-based emission estimates for Los Angeles (for the 1990s and 2000s) suggest that the CO emissions are underestimated in the inventory, which results in the higher inventory NOx/CO ratios.

Description: This global study, which has been coordinated by the World Meteorological Organization Global Atmospheric Watch (WMO/GAW) programme, aims to understand the behaviour of key air pollutant species during the COVID-19 pandemic period of exceptionally low emissions across the globe. We investigated the effects of the differences in both emissions and regional and local meteorology in 2020 compared with the period 2015–2019. By adopting a globally consistent approach, this comprehensive observational analysis focuses on changes in air quality in and around cities across the globe for the following air pollutants PM2.5, PM10, PMC (coarse fraction of PM), NO2, SO2, NOx, CO, O3 and the total gaseous oxidant (OX = NO2 + O3) during the pre-lockdown, partial lockdown, full lockdown and two relaxation periods spanning from January to September 2020. The analysis is based on in situ ground-based air quality observations at over 540 traffic, background and rural stations, from 63 cities and covering 25 countries over seven geographical regions of the world. Anomalies in the air pollutant concentrations (increases or decreases during 2020 periods compared to equivalent 2015–2019 periods) were calculated and the possible effects of meteorological conditions were analysed by computing anomalies from ERA5 reanalyses and local observations for these periods. We observed a positive correlation between the reductions in NO2 and NOx concentrations and peoples’ mobility for most cities. A correlation between PMC and mobility changes was also seen for some Asian and South American cities. A clear signal was not observed for other pollutants, suggesting that sources besides vehicular emissions also substantially contributed to the change in air quality. As a global and regional overview of the changes in ambient concentrations of key air quality species, we observed decreases of up to about 70% in mean NO2 and between 30% and 40% in mean PM2.5 concentrations over 2020 full lockdown compared to the same period in 2015–2019. However, PM2.5 exhibited complex signals, even within the same region, with increases in some Spanish cities, attributed mainly to the long-range transport of African dust and/or biomass burning (corroborated with the analysis of NO2/CO ratio). Some Chinese cities showed similar increases in PM2.5 during the lockdown periods, but in this case, it was likely due to secondary PM formation. Changes in O3 concentrations were highly heterogeneous, with no overall change or small increases (as in the case of Europe), and positive anomalies of 25% and 30% in East Asia and South America, respectively, with Colombia showing the largest positive anomaly of ~70%. The SO2 anomalies were negative for 2020 compared to 2015–2019 (between ~25 to 60%) for all regions. For CO, negative anomalies were observed for all regions with the largest decrease for South America of up to ~40%. The NO2/CO ratio indicated that specific sites (such as those in Spanish cities) were affected by biomass burning plumes, which outweighed the NO2 decrease due to the general reduction in mobility (ratio of ~60%). Analysis of the total oxidant (OX = NO2 + O3) showed that primary NO2 emissions at urban locations were greater than the O3 production, whereas at background sites, OX was mostly driven by the regional contributions rather than local NO2 and O3 concentrations. The present study clearly highlights the importance of meteorology and episodic contributions (e.g., from dust, domestic, agricultural biomass burning and crop fertilizing) when analysing air quality in and around cities even during large emissions reductions. There is still the need to better understand how the chemical responses of secondary pollutants to emission change under complex meteorological conditions, along with climate change and socio-economic drivers may affect future air quality. The implications for regional and global policies are also significant, as our study clearly indicates that PM2.5 concentrations would not likely meet the World Health Organization guidelines in many parts of the world, despite the drastic reductions in mobility. Consequently, revisions of air quality regulation (e.g., the Gothenburg Protocol) with more ambitious targets that are specific to the different regions of the world may well be required.

Description: Emission inventories are a critical basis for air quality and climate modeling, as well as policy decisions. Non-methane volatile organic compounds (NMVOCs) are key precursor compounds in ozone and secondary organic aerosol formation. Accurately representing NMVOCs in emission inventories is crucial for understanding atmospheric chemistry, the impact of policy measures, and climate projections. Improving NMVOC representation in emission inventories is fraught with challenges, ranging from the lack of (long-term) NMVOC measurements, limited efforts in updating emission factors, to the diversity of NMVOC species reactivity. Here we take an initial step to evaluate the representation of urban NMVOC speciation in an emission inventory (EDGARv4.3.2 and EDGARv6.1) at the global level. To compare the urban measurements of NMVOCs to the emission inventory estimates, ratios of individual NMVOCs to acetylene are used. Owing to limitations in measurement data and grouping of NMVOCs in emission inventories, the comparison includes only a limited number of alkanes, alkenes, and aromatics. Results show little to no agreement between the ratios in the observations and those in the global emission inventory for the species compared (r2 0.01–0.20). This could be related to incorrect speciation profiles and/or spatial allocation of NMVOCs to urban areas. Regional emission inventories show better agreement among the ratios (r2 0.43–0.70). The inclusion of oxygenated species in NMVOC measurements, as well as greater global coverage of measurements could improve representation of NMVOC species in emission inventories, and a mosaic of regional inventories may be a better approach.