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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 25 (1996), S. 303-312 
    ISSN: 1573-1111
    Keywords: Synthetic zeolite ZSM5 ; silver ; silver iodide ; ac conductivity measurements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A composite material made up of AgI and the potassium form of the synthetic zeolite ZSM5 has been prepared by treating the silver form of ZSM5 with potassium iodide. The composite has been characterised by X-ray powder diffractometry, IR and X-ray photoelectron spectroscopy, electron microsonde analyses and ac conductivity measurements. The Agl content in the composite material is 11.5%. On the basis of the conductivity data obtained for the composite material as well as for K-ZSM5, Ag-ZSM5, microcrystalline AgI and a physical mixture of AgI and K-ZSM5, it has been inferred that, in the composite material, AgI forms a thin conductive shell on the surface of the K-ZSM5 particles.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of inclusion phenomena and macrocyclic chemistry 31 (1998), S. 131-143 
    ISSN: 1573-1111
    Keywords: synthetic mordenite ; silver ; silver iodide ; ac conductivity measurements
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A composite material made up of AgI and the potassium form of mordenite has been prepared by treating the silver form of synthetic mordenite with potassium iodide. The composite as well as the silver and potassium forms of mordenite have been characterised by X-ray powder diffractometry, X-ray photoelectron spectroscopy, EDS analyses and ac conductivity measurements. It has been inferred that, in the composite material, AgI grows at the entrance of the zeolite channels without forming a continuous conducting phase. The silver form of mordenite has been proved to be a silver ion conductor by dc conductivity measurements.
    Type of Medium: Electronic Resource
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