ISSN:
0268-2605
Keywords:
ytterbium-ytterbium diiodide
;
vic-diaminoalkene
;
deoxygenative coupling
;
amide
;
samarium-samarium diiodide
;
thioamide
;
selenoamide
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Deoxygenative coupling of aromatic amides takes place successfully by the use of a mixed system comprising of ytterbium metal and ytterbium diiodide, providing the corresponding vic-diaminoalkenes in good yields. The same reaction does not take place if Yb metal or YbI2 is used alone. These results suggest novel enhancement of reducing ability by the combination of ytterbium(0) and ytterbium(II) diiodide. The Yb/YbI2 system is also effective for dethiolative coupling of thioamides, as sulfur analogues of amides. This paper also deals with reductive coupling of thioamides and selenoamides by using an Sm/SmI2 mixed system.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590090514
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