ISSN:
1572-8862
Keywords:
Dinuclear
;
cluster
;
diphosphine
;
metal-metal bond
;
heterobimetallic
;
oxidative-addition
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The “short-bite” ligands CH2(PR 2)2 or CH(PR 2)3 (R = Me, Ph),RN(PX 2)2 (R=H, Me, Et;X = F, OR′ (R′= Me, Et, i-Pr, Ph), Ph),RE(CH2 ER2)2 (E = P, As;R = Me, Ph ), Ph2 P(2-C5H4N) and related species are particularly versatile for the synthesis of di- and polynuclear complexes which frequently possess metal-metal bonds. In addition to homometallic products, these ligands often permit the directed synthesis of heterometallic complexes. Selected aspects of the chemistry of these complexes are also reviewed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01169695
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