ISSN:
1573-4846
Keywords:
hybrid copolymers
;
nano-building blocks
;
oxo-hydroxo organotin clusters
;
119Sn-NMR
;
methacrylate
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Hybrid organic-inorganic copolymers have been prepared following the nano-building blocks approach. The oxo-hydroxo butyltin macro-cation, (BuSn)12O14(OH)6 2+ , which is prepared by hydrolysis of butyltin tri-isopropoxide, is first functionalized by anchoring onto it methacrylate groups through electrostatic interactions. Then, to turn these isolated nano-building blocks into hybrid copolymers, they were assembled by initiating the organic polymerization of the methacrylate functions. 13 C and 119Sn NMR, in the solid state, and QELS evidences of the formation of hybrid organic-inorganic copolymers are reported.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1018374932557
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