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  • 1
    ISSN: 1612-1112
    Keywords: Concentration of organics ; Uncoated capillary columns ; Solvent desorption
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A novel technique has been developed for the analysis of trace organics in aqueous solutions. Concentration of organics is effected by passage of the solution being analysed through uncoated plastic or metal capillaries as reported. The concentrated organics are then desorbed from the capillary using an organic solvent, and the desorbed solution is subsequently analysed by gas chromatography. Organics trapped inside a variety of columns have been recovered by solvent desorption in this manner using a number of different solvents, mixed solvents, different solvent volumes, different solvent flow rates through the capillary column and at different desorption temperatures, and the effects of these variables on the efficiency of desorption are discussed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Concentration effects ; Uncoated capillary columns ; Trace organics ; Large aqueous volumes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new technique has been developed for the concentration of organics in aqueous solutions. Volumes greater than 100 ml can be utilized in this system, which previously could not have been done without a distillation or solvent extraction procedure. The method is based on the passage of the solution through uncoated capillary columns of various materials such as polyethylene, copper, aluminum, nickel, and many other metal and/or polymer columns of different dimensions. It is possible to achieve trace level analysis at the ppb to ppt level without the interferences inherent in other existing methods. The purification of solvents has been successfully demonstrated in this preliminary study, and will be discussed along with our suggestions for future investigations.
    Type of Medium: Electronic Resource
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