ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • ROMP  (1)
  • coalescence  (1)
  • integrally-skinned asymmetric membranes  (1)
  • 1
    Electronic Resource
    Electronic Resource
    A qualitative skin layer formation mechanism for membranes made by dry/wet phase inversion (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 419-427 
    Details
    ISSN: 0887-6266
    Keywords: integrally-skinned asymmetric membranes ; skin layer formation ; dry/wet phase inversion process ; capillary pressure ; surface tension ; coalescence ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Optimized membranes made by a dry/wet phase inversion process using forced-convective evaporation consist of an ultrathin and pore-free skin layer supported by a nodular transition layer underlying open-cell, sponge-like substructure. It is suggested that the out-ermost region of such case membranes undergo phase separation by spinodal decomposition in the initial stages of the evaporation process. As a result of the small scale of phase separation present in polymer-solvent systems, an appreciable capillary pressure occurs in the interstitial space filled with the polymer-poor phase in contact with air. The resulting force acts normal to the membrane-air interface, which tends to consolidate the polymer-rich phase to form a nonporous surface layer. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/polb.1993.090310406
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Gas permeation and sorption studies on stereoregular polynorbornene (1997)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 91-99 
    Details
    ISSN: 0887-6266
    Keywords: polynorbornene ; gas separation ; membranes ; permeation ; sorption ; ring-opening metathesis polymerization ; ROMP ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Advances in the field of membrane gas separation over the past decade have encouraged the search for even better polymers and membranes for gas separation. They also have motivated studies on the relationship between the structure and the gas transport properties of different classes of polymers. Interest has recently been demonstrated in the literature in norbornene polymers with different side groups. These polymers can easily be prepared via ring-opening metathesis polymerization (ROMP) of norbornene (bicyclo[2.2.1]hept-2-ene) derivatives. So far, information on the microstructure of the polymers is scarce, so little is known about the influence of stereochemistry and tacticity of the polymer on gas separation properties. In this work, we present gas permeability and selectivity data for stereoregular unsubstituted polynorbornene. It will be shown that a high order of tacticity has a positive effect on both permeation and separation results. © 1997 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...