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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of wood science 44 (1998), S. 361-368 
    ISSN: 1611-4663
    Keywords: Aluminum sulfate ; Aluminum compounds ; Adsorption ; Wet-end ; Pulp fiber
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Various aluminum compounds were added to pulp suspensions, and the adsorption behavior of their aluminum components on pulp fibers was studied. Aluminum contents in the handsheets were determined using an energy dispersive X-ray analyzer attached to a scanning electron microscope and an X-ray fluorescence analyzer. Although aluminum contents in the handsheets increased with increasing additions of the aluminum compounds, the detailed adsorption patterns varied among the aluminum compounds used. Their chemical structures and the pH values of the pulp suspensions greatly influence the adsorption behavior. When fines are present in the pulp suspensions, the aluminum components are predominantly adsorbed on the fines, probably due to their larger surface areas or the higher carboxyl contents compared to those of coarse fibers. Not only aluminum flocs but also far smaller components such as various aluminum cations seemed to be adsorbed on pulp fibers. Most aluminum flocs, which are formed in pulp suspensions by reacting with OH and entrapped in a fiber matrix by filtration effects, are removable by repeated mechanical agitation of the pulp suspensions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of wood science 45 (1999), S. 154-160 
    ISSN: 1611-4663
    Keywords: Aluminum sulfate ; Paper ; Retention ; Wetend ; Pulp fiber
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Handsheets were prepared with aluminum sulfate under various conditions of pulp suspension, and factors influencing retention behavior of aluminum components on the handsheets were studied on the basis of their aluminum contents. When deionized water was used in the handsheet-making process, aluminum contents in the handsheets had a plateau level of 0.7mg/g in the range of 1%–8% Al2(SO4)3 addition levels on dry weight of pulp. On the other hand, when tap water was used aluminum contents increased up to 5.6 mg/g, increasing the Al2(SO4)3 addition levels to 8%. The high aluminum contents in the handsheets are explained in terms of pH and the presence of calcium ions from the tap water used. Cationic aluminum species, which are formed from aluminum sulfate added to pulp suspensions, are primarily adsorbed on pulp fibers by electrostatic interactions with carboxyl groups in the pulp, competing with OH− ions in water. These aluminum components, once adsorbed on pulp fibers by ionic interactions, are not removed from the fibers by extending the stirring time of the pulp suspensions.
    Type of Medium: Electronic Resource
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