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Estimation of prediction error for samples within the calibration range (1992)

Karstang, Terje V. ; Toft, Jostein ; Kvalheim, Olav M.

New York, NY : Wiley-Blackwell

Journal of Chemometrics 6 (1992), S. 177-188

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ISSN: 0886-9383

Keywords: PLS ; Prediction error ; Background constituents ; Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A modification of a technique proposed by Lorber and Kowalski for the estimation of prediction errors is presented. The method is applied to five data sets. The results show that for some data sets the estimated prediction errors are close to the actual prediction errors for samples within the calibration range, while samples outside the calibration range must be background corrected before quantification of the prediction error.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cem.1180060403

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