ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (2)
  • Polymer and Materials Science  (1)
  • Polymer properties  (1)
Collection
  • Articles  (2)
Source
Keywords
Publisher
Years
Topic
  • 1
    Electronic Resource
    Electronic Resource
    Elastic Properties of Polymer Networks (1996)
    Springer
    Journal of molecular modeling 2 (1996), S. 293-299 
    Details
    ISSN: 0948-5023
    Keywords: Polymers networks ; Dynamics ; Polymer properties ; Microscopic models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Many fundamental questions for the understanding of polymer melts and networks are more suitably addressed by current computer simulations than by experiments. The reason is that simulations have simultaneous access to the microscopic structure and the macroscopic behavior of well-defined model systems. The coarse-grained models used often bear little relation to actual chemical species. This is justified by the experimentally established universality of polymer dynamics and no limitation for the test and development of theories which are directed at these universal aspects. The difficulties already encountered on this level will be illustrated for entanglements between polymers which dominate the dynamic in dense systems. For practical purposes it would, of coarse, be desirable to predict the characteristic length and time scales of experimental systems from the chemical structure of the polymer chains. Due to the extremely long relaxation times it is impossible to achieve this in brute-force simulations of truely microscopic models. Systematic coarse-graining combined with a better theoretical understanding seem to offer a practical alternative.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s0089460020293
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Evidence for the time-temperature superposition principle from Monte-Carlo simulations of the glass transition in two-dimensional polymer melts (1992)
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Theory and Simulations 1 (1992), S. 275-286 
    Details
    ISSN: 1018-5054
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The bond fluctuation model on a square lattice with a bond-length dependent potential exhibits in simulations of slow cooling a kinetic glass transition where the system falls out of equilibrium. Extending previous work, the relaxation functions of gyration radius and end-to-end distance, and the bond autocorrelation function of the polymers are presented and related to the time-dependent displacements of inner monomeric units and center of gravity of the whole chains, respectively. Over a wide temperature range the data can be collapsed on master curves satisfying the time-temperature superposition principle for Rouse dynamics.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mats.1992.040010501
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...