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Low temperature oxidative conversion of methane to syngas over NiO-CaO catalyst (1992)

Choudhary, V. R. ; Rajput, A. M. ; Prabhakar, B.

Springer

Catalysis letters 15 (1992), S. 363-370

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ISSN: 1572-879X

Keywords: Methane conversion ; synthesis gas ; nickel-calcium oxide

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Catalytic partial oxidation of methane over NiO-CaO (with or without its prereduction by H2) at low temperatures (⩽ 973 K) under non-equilibrium conditions yields syngas (H2/CO ratio ≈ 2.0) with high conversion/selectivity and extremely high productivity. If required, the H2/CO ratio can be increased by adding water vapour to the feed. Product selectivity is controlled by the process kinetics and also the reaction path is different from that observed for the high-temperature non-catalytic and catalytic processes operating at equilibrium.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00769159

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