ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Chemiluminescence of Diradicals from Lepidopterene, Dibenzylidenetriasterane, and DiphenylbicyclooctadieneThe hydrocarbons lepidopterene (1), sym-dibenzylidene-dimethyltriasterane (5), and 2,6-diphenylbicyclo[3.3.0]octa-2,6-diene (8) are sources of intense emission of red light upon UV-excitation under specified experimental conditions (solutions, glassy media, crystals). These unusual observations are interpreted in terms of initial diradical formation and their subsequent decay to intramolecular exciplexes and triplet excimers, resp., which undergo the radiative decay.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801131227
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