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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Space science reviews 92 (2000), S. 177-200 
    ISSN: 1572-9672
    Keywords: Solar Nebula ; Kinetics ; Thermochemistry ; Magnetite ; Troilite ; Water ; Hydrous Minerals ; Hydration ; Oxidation ; Volatiles ; Serpentine ; Talc ; Brucite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Thermochemical equilibrium calculations predict gas phase, gas-grain, and solid phase reactions as a function of pressure and temperature in the solar nebula. However, chemical reactions proceed at different rates, which generally decrease exponentially with decreasing temperature. At sufficiently low temperatures (which vary depending on the specific reaction) there may not have been enough time for the predicted equilibrium chemistry to have taken place before the local environment cooled significantly or before the gaseous solar nebula was dispersed. As a consequence, some of the high temperature chemistry established in sufficiently hot regions of the solar nebula may be quenched or frozen in without the production of predicted low temperature phases. Experimental studies and theoretical models of three exemplary low temperature reactions, the formation of troilite (FeS), magnetite (Fe3O4), and hydrous silicates, have been done to quantify these ideas. A comparison of the chemical reaction rates with the estimated nebular lifetime of 0.1-10 million years indicates that troilite formation proceeded to completion in the solar nebula. Magnetite formation was much slower and only thin magnetite rims could have formed on metal grains. Hydrous silicate formation is predicted to be even slower, and hydrous silicates in meteorites and interplanetary dust particles probably formed later on the parent bodies of these objects, instead of in the solar nebula.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-07-19
    Description: The magnetospheric ion population of Jupiter is dominated by the 1000 kg/s of iogenic material constantly ejected by IO volcanism as neutral gas (approx. 1 kg/s goes out as high speed dust grains), subsequent atmospheric losses to the IO torus, and radial transport of torus ions throughout the magnetosphere. As that magnetosphere is greatly distended in radial size by the iogenic plasma loading, so are surfaces of the other Galilean moons also significantly, and perhaps even dominantly, affected by iogenic plasma bombardment, e.g. at the level up to 0.2 kg/s heavy ions (mostly O and S) onto Europa as per local plasma ion measurements. In comparison, cometary impacts onto IO deliver about 0.02 kg/s of impact ejecta to Europa via ballistic transfer through the Jupiter system. The magnetosphere of this system operates as a powerful engine to produce and transport ions from the IO source to the surfaces of these other moons, and any future orbiter missions to these moons must account for surface distributions of the iogenic material and its chemical effects before real assessments can be made of sensible chemical materials otherwise arising from primordial formation and subsequent evolution of these moons. This is a fundamental problem of space weathering that must be addressed for all planetary bodies with thin atmospheres and direct surface exposure to their space plasma environments. Long-standing debates from Galileo Orbiter measurements about the origins of hydrate sulfates at Europa present examples of this problem, as to whether the sulfates arise from oceanic minerals or from iogenic sulfur chemistry. Any orbiter or landed mission to Europa for astrobiological investigations would further need to separate the potential chemical biosignatures of life or its precursors from the highly abundant background of iogenic material. Although no single ion carries a tag identifying it as of iogenic or other origin, the elemental abundance distributions of ions to be measured throughout the jovian magnetosphere and in the local moon environments can act as tracers if we know from direct measurements and models the distributions at the mostly likely sources, i.e. at IO. However, our knowledge of these abundances are very limited from earlier in-situ and remote measurements, mainly confined to major (S, O) and some minor (Na, K, Cl) species with abundances at or above a few percent relative to O. Future in-situ plasma measurements by the planned Jupiter Europa Orbiter and Jupiter Ganymede Orbiter missions should extend the abundance coverage to minor and even trace elemental species. For Europa astrobiological investigations it is also important to specify iogenic inputs and surface processing of isotopic species. We discuss the range of abundance distributions arising from models for IO hot volcanic emissions, and from the subsequent dynamics of ion injection, magnetospheric transport, and icy moon surface bombardment.
    Keywords: Geophysics
    Type: GSFC.CPR.4482.2011 , Geophysical Research Abstracts; 13; EGU2011-5075-4|European Geosciences Union General Assembly 2011; Apr 03, 2011 - Apr 08, 2011; Vienna; Austria
    Format: application/pdf
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