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  • 1
    ISSN: 1573-0662
    Keywords: Tropospheric ozone ; ozone precursors ; photochemistry ; nitrogen oxides ; rural ozone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The seasonal and diurnal variations of ozone mixing ratios have been observed at Niwot Ridge. Colorado. The ozone mixing ratios have been correlated with the NO x (NO+NO2) mixing ratios measured concurrently at the site. The seasonal and diurnal variations in O3 can be reasonably well understood by considering photochemistry and transport. In the winter there is no apparent systematic diurnal variation in the O3 mixing ratio because there is little diurnal change of transport and a slow photochemistry. In the summer, the O3 levels at the site are suppressed at night due to the presence of a nocturnal inversion layer that isolated ozone near the surface, where it is destroyed. Ozone is observed to increase in the summer during the day. The increases in ozone correlate with increasing NO x levels, as well as with the levels of other compounds of anthropogenic origin. We interpret this correlation as in-situ or in-transit photochemical production of ozone from these precursors that are transported to our site. The levels of ozone recorded approach 100 ppbv at NO x mixing ratios of approximately 3 ppbv. Calculations made using a simple clean tropospheric chemical model are consistent with the NO x -related trend observed for the daytime ozone mixing ratio. However, the chemistry, which does not include nonmethane hydrocarbon photochemistry, underestimates the observed O3 production.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0662
    Keywords: O3 ; Ox ; boundary layer ; lower troposphere ; Europe ; distribution ; seasonal variation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Surface ozone data from 25 Europeanlow-altitude sites and mountain sites located between79°N and 28°N were studied. The analysiscovered the time period March 1989–February 1993.Average summer and winter O3 concentrations inthe boundary layer over the continent gave rise togradients that were strongest in the north-west tosouth-east direction and west-east direction, respectively. WintertimeO3 ranged from 19 to 27 ppbover the continent, compared to about 32 ppb at thewestern border, while for summer the continentalO3 values ranged between 39 and 56 ppb and theoceanic mixing ratios were around 37 ppb. In the lowerfree troposphere average wintertime O3 mixingratios were around 38 ppb, with only an 8 ppbdifference between 28°N and 79°N. For summerthe average O3 levels decreased from about 55 ppbover Central Europe to 32 ppb at 79°N. Inaddition, O3 and Ox(= O3 + NO2)in polluted and clean air were compared. Theamplitudes of the seasonal ozone variations increasedin the north-west to south-east direction, while thetime of the annual maximum was shifted from spring (atthe northerly sites) to late summer (at sites inAustria and Hungary), which reflected the contributionof photochemical ozone production in the lower partsof the troposphere.
    Type of Medium: Electronic Resource
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  • 3
    Publication Date: 2019-07-13
    Description: Ten data sets covering the period 1954-2000 are analyzed to show a 1% per year increase in stratospheric water vapor. The trend has persisted for at least 45 years, hence is unlikely the result of a single event but rather indicative of long-term climate change. A long-term change in the transport of water vapor into the stratosphere is the most probable cause.
    Keywords: Environment Pollution
    Type: Paper-2000GL012502 , Geophysical Research Letters (ISSN 0094-8276); 28; 7; 1195-1198
    Format: text
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