ISSN:
0009-2940
Keywords:
Diboranes
;
Transition-metal boryl complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reaction of Na[(Cp)Fe(CO)2] and Na[(Cp)W(CO)3] with B2(NMe2)2Cl2 yields the first transition metal-substituted diboranes [Cl(Me2N)B-B(NMe2)M(Cp)(CO)n] [M(Cp)(CO)n = Fe(Cp)(CO)2, W(Cp)(CO)3] (1a, b). The compounds were characterized in solution by NMR methods and in the crystal by X-ray structural determination.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19961290919
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