Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
12 (1980), S. 261-270
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The treatment used for diffusion-controlled reactions is extended to the case when the final jumplike step of the reagent approach differs essentially from the preceding diffusion. In terms of the model proposed it is possible to take into account, in a simple way, chemical inhomogeneity of the reagents when the in-cage reaction rate depends on the pair state (for example, on the molecular orientation). In this connection the reaction can be controlled either by the reagent intrusion into the solvation shell of the partner, or by the in-cage relaxation.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550120407
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