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  • 1
    Publication Date: 2023-06-08
    Description: The knowledge about thermo-mechanical properties of granite is still limited to some extent. Individual measurements are necessary to obtain reliable properties for specific granite types. A reliable numerical model of thermal cracking behaviours of granite exposed to extreme high temperatures (e.g. 800–1000 °C) is missing. In this study, the impact of temperature up to 1000 °C on physical, mechanical, and thermal properties as well as thermo-mechanical coupled behaviour of Eibenstock granite was investigated by laboratory testing and numerical simulations. The physical properties including mineral composition, density, P-wave velocity, and open porosity are measured to be temperature dependent. Uniaxial compression and Brazilian tests were carried out to measure uniaxial compressive strength (UCS), Young’s modulus, stress–strain relationship, and tensile strength of Eibenstock granite before and after thermal treatment, respectively. Thermal properties including specific heat, thermal conductivity, thermal diffusivity, and linear thermal expansion coefficient are also measured and found to be temperature dependent, especially the expansion coefficient which shows a steep increase around 573 °C as well as at 870 °C. The numerical simulation code FLAC3D was used to develop a numerical scheme to simulate the thermal-induced damage of granite at high temperatures. Statistical methods combined with real mineral composition were used to characterize the heterogeneity of granite. The numerical model is featured with reliable temperature-dependent parameters obtained from laboratory tests. It can well reproduce the laboratory results in form of thermal-induced micro- and macrocracks, as well as the stress–strain behaviour and the final failure pattern of Eibenstock granite after elevated temperatures up to 1000 °C. The simulation results also reveal that the thermal-induced microcracks are randomly distributed across the whole sample. Although most thermal-induced damages are tensile failures, shear failure begins to develop quickly after 500 °C. The obvious UCS reduction in granite due to heating is mainly caused by the increase in shear failure. The simulation also shows that the dominant impact of α–β quartz transition is widening pre-existing cracks rather than the formation of new microcracks.
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Keywords: ddc:550.724 ; Granite property ; Heterogeneity ; Numerical simulation ; Thermo-mechanical behaviour ; Thermal damage
    Language: English
    Type: doc-type:article
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 2413-2424 
    ISSN: 0887-624X
    Keywords: PEEK ; functionalization ; bromination ; functional polymer ; substituted PEEK ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bromomethyl poly (aryl ether ether ketone) has been prepared from methyl poly (aryl ether ether ketone) (MePEEK) and has been used as the precursor to many forms of functionalized PEEK. MePEEK was brominated directly with bromine. Bromination takes place exclusively at the methyl group. The reaction conditions for bromination have been studied. The bromination level can be controlled by the amount of bromine used, up to 90% of the methyl groups can be brominated to mono-bromo and di-bromo methyl PEEK. Modification reactions have been carried out on the brominated methyl PEEK. The bromomethyl group has been converted to different functional groups, such as — CH2OH, — CH2OCH3, — COOCH3, — CH2CN, — CH2COOH — CH2OCOCH3, — CH2N+H (CH2CH3)2Br-, — CH2N (CH2CH3)2, — CH2N+ (CH2CH3)3 Br-. Published 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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