ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthetic procedures have been developed for the preparation of ligands bearing two to six pendent, unsubstituted or substituted 2, 2′-bipyridine groups attached to acyclic (tripode, tetrapode) and macrocyclic (triazanonade-cane, cyclam, hexacyclen, bis(bipyrido)hexaazamacrocycle) polyamines. Ligands 1-5 have been obtained in high yield by condensation of 6-(bromomethyl)-2, 2′-bipyridine (9b) with the corresponding amines in the presence of NaOH, H2O, and MeOH. Ligands 6-8 have been prepared in good yield by condensation of 9b or the di- or tetrasubstituted mono (bromomethyl) bipyridine 10b or 11b, respectively, with the corresponding amines in the presence of Na2CO3 and MeCN. Ligand 1 forms hemi-cage complexes with RuII, FeI, CrII, and CrIII cations and trinuclear complexes with [RuCl2(bpy)2] and [ReCl(CO)5]. Tetrapode 2 and hexapode 4 gave tetranuclear and dinuclear complexes, respectively, by reaction with Fe11 salts. These complexes possess a variety of interesting physical and chemical properties.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19900730502
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