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  • 1
    Electronic Resource
    Electronic Resource
    Raman scattering of α-toluenethiol adsorbed on silver sol (1991)
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 22 (1991), S. 339-344 
    Details
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Surface-enhanced Raman scattering (SERS) of α-toluenethiol adsorbed on a silver surface has been investigated. The controversial vibrational assignment of the molecule was refined by comparing the SERS spectra with the ordinary Raman spectra of α-toluenethiol, α-toluenethiolate, benzyl chloride and their deuterated species. Based on the assignment and the SERS selection rule, it is proposed that α-toluenethiol is adsorbed as a thiolate on silver via its sulphur atom with both the methylene group and benzene ring oriented approximately parallel to the metal surface.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jrs.1250220607
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