ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A summary of the mass spectra of metal dithiocarbamate complex salts (ML2 and ML3) is presented. Only divalent metal dithiocarbamate ions without an electronic configuration containing an inert s-orbital electron pair exhibited both expulsion of a ligand radical (L) and the neutral even electron species (L-H) generated from the ligand via hydrogen transfer to the metal-containing fragment ion. Divalent metal dithiocarbamate ions can be generated either by direct electron impact ionization of gas phase ML2 molecules or ionization of ML3 molecules followed by loss of a ligand radical. A highly stable sp2 hybridized, gas phase ion of a monobidentate lead dithiocarbamate complex is proposed.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210160104
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