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  • Age; AGE; Age, range; Antimony; Arsenic; BAMBUS; Barium; Bismarck Sea; Bismuth; Cadmium; Calcium; Chromium; Cobalt; Copper; DEPTH, water; Description; Event label; Gallium; Germanium; Gold; hydrothermal vent; Indium; Iron; LATITUDE; Lead; LONGITUDE; Manganese; Mercury; mineral weathering; Molybdenum; Name; Nickel; Oxygen; Radium-226, standard deviation; Radium-226/Barium activity ratio; Radium-226/Barium activity ratio, standard deviation; Radium-226 activity per mass; Remote operated vehicle; ROV; Sample ID; Sample type; Selenium; Silicon dioxide; Silver; SO216; SO216-27-1; SO216-29-1; SO216-31-1; SO216-43-1; SO216-47-1; SO216-49-1; SO216-53-1; Sonne; Status; Strontium; Sulfur, elemental; sulphide chimney; Tellurium; Tin; Titanium; Zinc  (1)
  • Polyethylene, energy band structures and electron distribution of ∼  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Theoretical chemistry accounts 50 (1978), S. 193-209 
    ISSN: 1432-2234
    Keywords: Polyethylene, energy band structures and electron distribution of ∼
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The electronic structure of polyethylene has been re-examined using Gaussian basis sets in anab initio solid-state method. Previous calculations were shown to possess a minor error in unit-cell coordinates and were corrected. Six basis sets were used and the results compared within the nearest-neighbour approximation. The effect on the calculation of increasing the number of interacting unit cells to five was studied. The latter produces no significant change in the C-H polarity; the overall conduction band width remains essentially the same but the Koopmans' ionization potential is displaced more towards the experimental value. An investigation was made into the effects of neighbouring strands on a central filament. We find that the Point Charge Perturbation model is a useful one in this context and yields a realistic interstrand distance. This is dominated by the hydrogen atoms. It is essentially unaffected by extension of the perturbing field to second neighbour strands.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2024-04-13
    Description: In this dataset, seven inactive massive sulfide chimneys, collected in the Manus Basin (Bismarck Sea, Papua New Guinea, SW Pacific) during SONNE cruise SO216 in 2011, are characterized with respect to mineralogical and geochemical composition as well as age. The samples originate from the PACManus (Snowcap, Fenway, Satanic Mills, Solwara 6, Solwara 8) and SuSu Knolls (North Su) hydrothermal vent fields that emit highly sulfidic fluids and feature poly-metallic sulfide chimneys and mounds. They were collected by the ROV QUEST (Marum Bremen) with the ROV's hydraulic arm. Ore petrology was performed on polished thin sections and shows that the chimneys were mainly composed of chalcopyrite (CuFeS₂), pyrite/marcasite (FeS₂), sphalerite (Zn(Fe)S), and bornite (Cu₅FeS₄) with a suite of other minor to rare minerals. The bulk geochemistry of the samples was determined on representative samples (several tens to hundreds of grams) by a combination of methods including ICP-OES, ICP-MS and Instrumental Neutron Activation. Some samples show elevated As-and Pb-concentrations (up to 3.2 wt.% As; up to 2.0 wt.% Pb), which is also reflected in the presence of tennantite and galena as well as other sulfosalts in thin sections. Five of the seven collected inactive chimney samples were dated using the ²²⁶Ra/Ba method. The youngest, yet clearly inactive sample was StM-R2 (Satanic Mills; 0 y ± 160 y) followed by Fw-R1 (Fenway; 1400 y ± 160 y), Sol8-R1 (Solwara 8; 1800 y ± 160 y) and Sol6-R1 (Solwara 6; 2093 y ± 267 y). The oldest dated chimney was NSu-R7 (North Su; 3183 y ± 236 y). The chimney samples were part of a study, in which 16S rRNA gene based community profiling of active (n=6) and inactive (n=7) sulfide chimneys from the Manus Basin (SW Pacific) was conducted. The diversity information in combination with radiometric dating was used to select a subset of inactive sulfide chimneys of different age for functional analyses on metagenomic (n=4) and metaproteomic (n=1) level.
    Keywords: Age; AGE; Age, range; Antimony; Arsenic; BAMBUS; Barium; Bismarck Sea; Bismuth; Cadmium; Calcium; Chromium; Cobalt; Copper; DEPTH, water; Description; Event label; Gallium; Germanium; Gold; hydrothermal vent; Indium; Iron; LATITUDE; Lead; LONGITUDE; Manganese; Mercury; mineral weathering; Molybdenum; Name; Nickel; Oxygen; Radium-226, standard deviation; Radium-226/Barium activity ratio; Radium-226/Barium activity ratio, standard deviation; Radium-226 activity per mass; Remote operated vehicle; ROV; Sample ID; Sample type; Selenium; Silicon dioxide; Silver; SO216; SO216-27-1; SO216-29-1; SO216-31-1; SO216-43-1; SO216-47-1; SO216-49-1; SO216-53-1; Sonne; Status; Strontium; Sulfur, elemental; sulphide chimney; Tellurium; Tin; Titanium; Zinc
    Type: Dataset
    Format: text/tab-separated-values, 267 data points
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