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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 50 (1990), S. 287-300 
    ISSN: 1432-0630
    Keywords: 68.45.v ; 81.60.Bn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The purpose of this paper is to provide a syntheses of experimental results regarding films formed on the surface of stainless steels. Such syntheses are attempted for the environments most studied. In each case the overview is presented with reference to the most important papers. Conflicting data are also presented and discussed. Based on the results of the prior studies, a four region model is proposed to describe the surface passive film and its breakdown.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 68.45.v ; 81.60.Bn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract This paper deals with the structure and composition of the passive film formed on the surface of two commercial stainless steels during immersion in 0.1 M NaCl for 0.5 h at 25, 60, and 90°C. The data shows that the passive films formed at 60 and 90°C by short-time solution exposure are very similar to these formed at 25°C, and are consistent with the three-factor model described previously: a hydrated layer in contact with the solution, an oxide layer consisting of iron and chromium oxides having maxima at depths of 3 and 10 Å, respectively, and a metallic layer enriched in nickel. There is a smooth transition between the layers, with the thickness of the outer two layers being about 15 Å.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0630
    Keywords: 68.45.v ; 81.60.Bn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract After immersion in a 0.1 M NaCl solution for 1 h at various controlled potentials, the surface films formed on two commercial stainless steels, 18–12 and 29-4-2, have been studied using a surface analysis technique ESCA (Electron Spectroscopy for Chemical Analysis) combined with ion etching. The influence of controlled potential in the lower region, between the OCP and the critical pitting potential, on the structure and chemical composition of the passive film is in limited agreement with the prior work. At higher controlled potentials above the pitting potential, the surface films consist of two components: the passive film and corrosion products. Changes to both oxidized chromium and metallic iron form major differences in the depth profiles in comparison with the previous results with the passive film. At higher controlled potentials oxidized alloying elements tend to the higher oxidation states on the outermost part of surface together with a possibility of enhanced adsorption of chloride ions. There is a great amount of oxidized molybdenum and chloride ions mainly from the corrosion products on the surface at higher applied potential. Their contents increase with the controlled potential.
    Type of Medium: Electronic Resource
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