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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 1905-1911 
    ISSN: 1434-193X
    Keywords: α,β-Epoxy ketones ; Rearrangements ; Zeolites ; Clays ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ---Various cyclic α,β-epoxy ketones rearranged to α-formyl ketones and/or vic-diones in the presence of catalytic amounts of zeolites and montmorillonite K10. This provides an excellent alternative to conventional homogeneous systems with respect to yields and workup. Differences in product distribution and type of products in the rearrangement of pulegone oxide could be reasonably explained by invoking different pathways for homogeneous and heterogeneous catalysts.
    Additional Material: 4 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1999 (1999), S. 837-846 
    ISSN: 1434-193X
    Keywords: Friedel-Crafts reaction ; Hydroxyalkylation ; Aromatics ; Epoxides ; Zeolites ; Clays ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: -Solid acids, such as zeolites and clays, catalyse the intramolecular hydroxyalkylation (cyclialkylation) of several arylalkyl epoxides in moderate to excellent conversions and selectivities. The use of solid acids in these cyclialkylations provides a cleaner, better alternative to conventional Lewis and Brønsted acids, enabling a more facile workup of reaction mixtures and, in several cases, better selectivities.
    Additional Material: 3 Ill.
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  • 3
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    In:  62. Jahrestagung der Deutschen Geophysikalischen Gesellschaft (Hannover 2002)
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/conferenceObject
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  • 4
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 5
    Publication Date: 2020-02-12
    Description: A wide-angle seismic profile across the western peninsulas of SW Ireland was performed. This region corresponds to the northernmost Variscan thrust and fold deformation. The dense set of 13 shots and 109 stations along the 120 km profile provides a detailed velocity model of the crust. The seismic velocity model, obtained by forward and inverse modelling, defines a five-layer crust. A sedimentary layer, 5-8 km thick, is underlain by an upper-crustal layer of variable thickness, with a base generally at a depth of 10-12 km. Two mid-crustal layers are defined, and a lower-crustal layer below 22 km. The Moho lies at a depth of 30-32 km. A low-velocity zone, which coincides with a well-defined gravity low, is observed in the central part of the region and is modelled as a Caledonian granite which intruded upper-crustal basement. The granite may have acted as a buffer to northward-directed Variscan thrusting. The Dingle-Dungarvan Line (DDL) marks a major change in sedimentary and crustal velocity and structure. It lies immediately to the north of the velocity and gravity low, and shows thickness and velocity differences in many of the underlying crustal layers and even in the Moho. This suggests a deep, pre-Variscan control of the structural development of this area. The model is compatible with thin-skinned tectonics, which terminated at the DDL and which incorporated thrusts involving the sedimentary and upper-crustal layers.
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/article
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  • 6
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    In:  Lithospheric structure, evolution and sedimentation in continental rifts : proceedings of the IGCP 400 Meeting, 20 - 22 March 1997, Dublin | Communications of the Dublin Institute for Advanced Studies : Series D, Geophysical Bulletin ; 48
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 7
    Publication Date: 2020-02-12
    Description: We employ P to S converted waveforms to investigate effects of the hot mantle plume on seismic discontinuities of the crust and upper mantle. We observe the Moho at depths between 13 and 17 km, regionally covered by a strong shallow intracrustal converted phase. Coherent phases on the transverse component indicate either dipping interfaces, 3-D heterogeneities or lower crustal anisotropy. We find anomalies related to discontinuities in the upper mantle down to the transition zone evidently related to the hot mantle plume. Lithospheric thinning is confirmed in greater detail than previously reported by Li et al., and we determine the dimensions of the low-velocity zone within the asthenosphere with greater accuracy. Our study mainly focuses on the temperature-pressure dependent discontinuities of the upper mantle transition zone. Effects of the hot diapir on the depths of mineral phase transitions are verified at both major interfaces at 410 and 660 km. We determine a plume radius of about 200 km at the 660 km discontinuity with a core zone of about 120 km radius. The plume conduit is located southwest of Big Island. A conduit tilted in the northeast direction is required in the upper mantle to explain the observations. The determined positions of deflections of the discontinuities support the hypothesis of decoupled upper and lower mantle convection.
    Keywords: 550 - Earth sciences
    Language: English
    Type: info:eu-repo/semantics/article
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  • 8
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    In:  64. Jahrestagung der Deutschen Geophysikalischen Gesellschaft (Berlin 2004)
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 9
    Publication Date: 2020-02-12
    Keywords: 550 - Earth sciences
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  • 10
    Publication Date: 2020-02-12
    Description: In February 1994, the Kenya Rift International Seismic Project crawled out two wide-angle reflection and refraction seismic profiles between Lake Victoria and Mombasa across southern Kenya. Our investigation of the data has revealed evidence for the presence of two upper mantle reflectors beneath southwestern Kenya, sometimes at short range, from seven shotpoints. Two-dimensional forward modelling of these reflectors using a pre-existing two-dimensional velocity-depth model for the crust [Birt, C.S., Maguire, RH.K., Khan, M.A., Thybo, H., Keller, G.R., Patel, J., 1997. The influence of pre-existing structures on the evolution of the Southern Kenya Rift Valley -- evidence from seismic and gravity studies. Tectonophysics 278, 211-242], has shown them to lie at depths of approximately 51 and 63 km. The upper reflector, denoted d(tief)1, shallows by about 5-10 km in the area beneath Lake Magadi, situated in the rift itself. Correlations for the deeper reflector, denoted de, are sparse and more difficult to determine, so it was not possible to define any shallowing corresponding to the surface expression of the rift. Only limited control exists over the upper mantle velocities used in the modelling. Immediately beneath the Moho we use a value of P(tief)n calculated from the crustal model, and constraints from previous refraction, teleseismic and gravity studies, to determine the velocity at depth. At the d(tief)1 reflector a reasonable velocity contrast was introduced to produce a reflector for modelling purposes. Beneath the d(tief)l reflector the velocity decreases to the average value over 3 km. Beneath the rift the velocity also rises across dl and again, decreases to the average value over the next 3 km. At the d(tief)2 reflector a similar model is used. This model accounts for the presence of the mantle reflectors seen in the data by using layers of thin higher velocity in a lower background velocity. Due to the uncertainty in the velocities the absolute position of both d(tief)1 and d(tief)2 could vary, but the relative upwelling beneath the rift is reasonably well constrained and data from four different shotpoints which indicate the shallowing show good agreement. A significant result of this study is that the continuity of the d(tief)1 reflector indicates that the sub-Moho lithosphere has not been substantially disrupted by mantle upwelling, even though probably thinned and stretched.
    Keywords: 550 - Earth sciences
    Type: info:eu-repo/semantics/article
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