ISSN:
0749-1581
Keywords:
Rhodium complexes INEPT 15N NMR
;
103Rh NMR
;
1H NMR
;
31P NMR
;
2,2′-bipyridyl
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
By the use of the INEPT pulse sequence it has been possible to obtain 15N and 103Rh NMR data on [RhH2(PPh3)2(bipy)]Cl (bipy = 2,2′-bipyridyl) containing natural abundance 15N and prove the stereochemistry; 1H and 31P NMR data are also reported for [RhH2(PPh3)2(bipy)]Cl which can be easily prepared in the pure state by the reaction of [RhCl(PPh3)3] or [Rh2Cl2(PPh3)4] with bipy ([Rh]: [bipy] = 1:1) under an H2 atmosphere.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260291307
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