ISSN:
1572-8854
Keywords:
1,10-Phenanthroline ligand
;
adduct
;
O,O′-diisopropyldithiophosphato
;
zinc complex
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The crystal and molecular structure of [Zn(phen)(S2P(OiPr)2)2] (Phen = 1,10-phenanthroline) has been determined by X-ray crystallography. It crystallizes in the Monoclinic system, space group C2/c, with lattice parameters a = 19.315(4), b = 10.438(2), c = 16.567(3)Å, β = 102.89 (3)°, and Z = 4. The complex has C2 symmetry. The coordination geometry of each Zn atom, by two S atoms from two (O,O′-diisopropyldithiophosphato) anions and by two N atoms from phenanthroline ligand, is that of a slightly distorted tetrahedron [Zn—S 2.2914(8)Å Zn—N 2.111(2)Å]. The Zn···S distances to the noncoordinated S atoms are long: 3.5276 Å, which are indicated that there are much weaker interactions between them.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1011303617063
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