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  • 1
    Publication Date: 2017-04-04
    Description: Italy is one of the most promising prone areas to study the CO2 behavior underground, the caprock integrity to the CO2 leakage, mostly in presence of pervious/geochemically active faults, due to a wide availability of CO2 rich reservoirs at a depth between 1 and 10 km, as highlighted by recent literature. These deep CO2 reservoirs generate at least 200 leakage areas at surface throughout Italy which have been defined “Diffuse Degassing Structures” (DDS) by INGV. These are widely studied by INGV institutionally by a long term convention with the Civil Protection Department (DPC) with the aim to catalog, monitor and assess the Natural Gas Hazard (NGH, namely the probability of an area to become a site of poisonous peri – volcanic gas exhalation from soils). More than 150 researcher of INGV are involved in monitoring areas affected by the CO2 presence underground and at surface, by continuous monitoring on-line networks (around 40 stations throughout Italy, including the Etna area, Aeolian Islands, Umbria region, Piemonte region, etc…) and discretely (9 groups of research were involved in the last years to localize, define and monitor almost all the DDSs in Italy), by sampling and analyzing chemical and isotopic compounds, useful to discriminate the origin, evolution and natural gas hazards of the examined DDS. In this paper, we will discuss some DDS catalogued and studied by a Rome INGV Research Unit (UR 11) which focused its work in Central Italy, throughout different DDS, also in relation to the diverse seismotectonic settings, to discover buried faults as possible gas leakage pathways, mostly if they are “geochemically” activated. In particular we discuss, among the discrete monitoring techniques exploited by INGV, soil gas surveying, which consists in a collection of gas samples from the soil zone not saturated (dry zone) to measure the geogas gaseous species both in fluxes (CO2, CH4, 222Rn) and in concentration (He, H2, H2S, helium, hydrogen, CO2, CH4, 222Rn), that permeate the soil pores. The total CO2 flux budget was calculated as “baseline” degassing rate of these “CO2 analogues”. A good discrete areal monitoring is prerequisite to design sound continuous monitoring network to monitor CO2 related parameters in liquid/gas phases, to review the protocol of the Annex II of the European Directivity on CCS.
    Description: Published
    Description: 2135-2142
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: N/A or not JCR
    Description: reserved
    Keywords: Diffuse Degassing Structures ; CO2 storage ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Soon after a 222Rn and 220Rn survey in soil gases, performed (June 2005) in the frame of the Diffuse Degassing in Italy risk assessment project, a moderate earthquake (Mw=4.6) occurred in the Anzio offshore, on August, 22, 2005, only 5 miles from the Tor Caldara Diffuse Degassing Structure (DDS onward). Having available the pre-earthquake 222Rn and 220Rn grid-map on around 50 soil-gas points and being 222Rn both a stress-pathfinder and a discriminative component of activated-faults, a mirrorlike survey was repeated on the same 50 sites, soon after the close earthquake. Later, during a quiescent-aseismic period (December, 2005), a CO2 flux survey was performed for the same 50 sites, adding detailed measurements (more than 100 sites) for the highest flux sectors. The aim of this survey was both to have an overall picture of the background CO2 flux and to calculate the total budget of CO2 flux throughout the DDS, to better interpret the 222Rn and 220Rn areal surveys before and after the seismic event. Herewith, we distinguish the contribution of organic, diffusive and advective CO2 flux. Hints of convection and strong degassing linked to the fracture field, inside the DDS, have been envisaged on selected points, where continuous monitoring stations could be strategic, for seismic, volcanic and NGH surveillance. Despite we found higher 222Rn values in soils after the earthquake, suggesting an enhanced local degassing probably linked to a stress signal throughout the DDS as a whole, the results highlight an unmodified shape and location of the 222Rn anomalies before and after the earthquake. This evidence excludes both that the activated seismogenic segment has affected in some ways both the DDS degassing patterns and that fracture field changed. A similar result could be expected if the activated fault was oriented along the DDS itself and reached the surface. This evidence is well correlated with the reconstructed focal mechanism of the earthquake, pertaining to the transfer structure of the Ardea Graben , located along a peripheral sector of the degassing Alban Hills volcano and intersecting the DDS Tor Caldara itself. The shape and location of 222Rn anomalies inside the DDS for both the surveys are strictly inversely correlated with the areal CO2 flux data. The geometry of the degassing pathways is probably linked to the barrier action (sealing power) of the clays cropping out in the study area. These clays are generated by the strong leaching of the outcropping sedimentary Pleistocene rocks due to the huge flux of volcanic gas -rich fluids.
    Description: Published
    Description: Perugia, Italy
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: tor caldara ; quiescent aseismic period ; diffuse degassing structure ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 3
    Publication Date: 2017-04-04
    Description: The 2009 L’Aquila seismic sequence, whose main shock (Ml 5.8, Mw 6.3) occurred on April 6th at 1:32 UTC, is still ongoing (August 2009) along the central Apenninic Belt (Abruzzo region, central Italy). The main earthquake was destructive and caused 300 casualties; its epicenter has been located at 42.35°N, 13.38°E, at a depth of around 10 km. The main shock was preceded by a long seismic sequence, started several months before (i.e., December 2008, with a total of 300 earthquakes with Mlmax = 4.0). After the April 6th main event, two other earthquakes struck the area on April 7th and 9th, with Ml 5.3 and 5.1, respectively. A lot of evidences stress the role of the pore-pressure evolution of deep fluids in generating the L’Aquila sequence (e.g. Vp/Vs anomalous ratio, Chiarabba C., 2009 personal communication) as occurred for the Umbria Marche (central Italy) 1997-1998 seismic sequence (Quattrocchi, 1999 and references herein). The entire sequence highlights more than one seismogenic segment activated along a main NW-SE-trending Apenninic lineament (Fig. 1). Soon after the strongest event, our group (UF “Fluid Geochemistry, Geological Storage and Geothermics”, Department Rome 1, INGV) carried out a geochemical study throughout the seismically activated area by sampling around 600 soil gas points and around 70 groundwater points (springs and wells). The main goal of this study was the comprehension of both the behaviour and the geometry of the activated fault segments by means the application of specific geochemical methods, already exploited in other Italian seismic and volcanic areas (Quattrocchi et al., 2000; Pizzino et al., 2004; Quattrocchi et al., 2008; Voltattorni et al., 2009).In particular, here we discuss only the results gathered by measuring soil gases, considering fluxes of CO2 and CH4 as well as concentrations of radon, CO2, CH4, He, H2, N2, H2S, O2, and other minor geogas (i.e. light hydrocarbons) in the main sectors of the activated seismic sequence (see the red box in figure 1). The geochemical measurements were addressed to more than one objective. One was to update a GIS of the co-seismic effects (associated to the earthquakes with magnitude greater than ML=5.0 and surveyed by our INGV EmerGeo Working Group) and their spatial and geometrical parameters in the local geological framework. More than 400 observation sites (fractures mainly) have been detected in an area of ~ 900 km2, part of which coupled with geochemical measurements in soils (fluxes and concentrations). Most of the surface effects have been observed also as regards the presence/absence at surface of deep fluids uprising (hot water, gas pools/fluxes, vapours, etc….) along and close to the previously mapped active faults (INGV Catalogue of Strong Historical earthquakes). Geochemical measurements in soils are very powerful to discriminate the numerous local surface effects (landslides, differential compaction, rock falling, etc) with respect to the real signatures of the expression at surface of the activated seismogenic segment. For earthquakes of moderate magnitude, such as the L’Aquila 2009 event, where the superficial effects could be absent or not evident, our geochemical method demonstrated to be strategic and potentially applicable in other worldwide seismic areas. Most ruptures with a structural significance have been observed along the Paganica Fault (elongated NW-SE); also the Bazzano and Monticchio-Fossa faults have been geochemically analysed; we searched the different behaviour of these structures as a whole, each having a different tectonic role (passive, active, transfer, crossing point, etc.), in determining the degassing observed at surface. The results highlight the maximum geochemical anomalies just along a minor anti-apenninic NE-SW transverse lineament; here, CO2 (up to 2000 [gm-2day-1]) and CH4 (up to 300 [gm-2day-1] anomalous fluxes were found soon after the main shock, remaining anomalous in the following months, but with lower values. Furthermore, just in correspondence of this lineament highest values of radon (up to 40.000 Bq/m3) were found. The transects perpendicular to the Paganica Fault clearly highlighted the role of the main fracture at surface (masked in few days) as preferential pathway for gases escaping from depth, as revealed by geochemical methods. The measured values are in any case not dangerous for the people’s health and minimise the problem of CO2-CH4 burst or explosions during strong earthquakes when these gases are stored naturally underground (km), as under these activated faults (as showed by the deep wells drilled in the area). Finally, the soundest sites to install 3 continuous monitoring stations, measuring the CO2 fluxes, were selected and the stations installed (Paganica, Bazzano and S. Gregorio sites) in cooperation with colleagues coming from the INGV geochemical department of Palermo (Sicily, southern Italy). The considered geochemical methods could be exploited along other faults in Italy and abroad by performing pre-main shock geochemical surveys to i) highlight earthquake preparation discovering anomalous degassing; ii) draw a picture of fault degassing before strong seismic events and, later, during a seismic sequence; iii) to highlight transverse lineaments among main fault segments, adding information where geo-structural expressions at surface are hidden.
    Description: Published
    Description: Damascus-Syria
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: L'Aquila ; Earthquake ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 4
    Publication Date: 2017-04-04
    Description: One of the most promising options to stabilize and reduce the atmospheric concentration of greenhouse gases is Carbon Capture and Storage (CCS). This technique consists of separating CO2 from other industrial flue gases and storing it in geological reservoirs, such as deep saline aquifers, depleted oil and/or gas fields, and unminable coal beds. A detailed reworking of all available Italian deep-drilling data was performed to identify potential storage reservoirs in deep saline aquifers. Data were organized into a GIS geo-database containing stratigraphic and fluid chemistry information as well as physiochemical characteristics of the geological formations. Caprock efficiency was evaluated via numerical parameterization of rock permeabilities, defining the “Caprock Quality Factor” (Fbp) for each well. The geo-database also includes strategic information such as the distribution of deep aquifers, seismogenic sources and areas, seismic events, Diffuse Degassing Structures, heat flow, thermal anomalies, and anthropogenic CO2 sources. Results allow the definition of potentially suitable areas for future studies on CO2 geological storage located in the fore-deep domains of the Alps and Apennines chains, where efficient marly-to-clayish caprocks lie above deep aquifers hosted in sands or limestones. Most of them are far form seismogenic sources and Diffuse Degassing Structures.
    Description: Published
    Description: 2968-2983
    Description: 3.8. Geofisica per l'ambiente
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: 5.4. Banche dati di geomagnetismo, aeronomia, clima e ambiente
    Description: 5.5. TTC - Sistema Informativo Territoriale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 storage ; Geo-database ; Caprock quality ; Aquifers ; Geological risk factors ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
    Publication Date: 2024-05-09
    Description: EnCana’s CO2 injection EOR project at Weyburn (Saskatchewan, Canada) is the focal point of a multi-faceted research program, sponsored by IEA GHG R&D and numerous international industrial and government partners including the European Community (BGS, BRGM, INGV and GEUS research providers), to find co-optimization of “CO2-EOR Production” and “CO2 -Geological Storage”, addressed to environmental purposes, in the frame of the Kyoto Agreement Policies. The Weyburn oil-pull is recovered from Midale Beds (at the depth of 1300-1500 m). This formation consists of Mississipian shallow marine carbonate-evaporites that can be subdivided into two units: i) the dolomitic “Marly” and ii) the underlying calcitic “Vuggy”, sealed by an anhydrite cap. Presently, around 3 billions mc of supercritical CO2 have been injected into the “Phase A1”injection area that includes around 90 oil producers, 30 water injectors and 30 CO2 injection wells, build up since September 2000. INGV has carried out a geochemical monitoring programme -approximately thrice yearly from pre-injection (“Baseline” trip, August 2000) to September 2004- performing trace element and dissolved gas analysis along with fluids sampling surveys, the latter being performed by the Canadian partners. The experimental data are the base of a geochemical modelling, i.e. the main goal of the present study. In the past, assumptions and gap-acceptance have been made in the literature in the frame of the geochemical modelling of CO2 geological storage, in order to reconstruct the reservoir conditions (pressure, pH and boundary conditions). As these parameters of deep fluids cannot be measured in-situ, all this information must be computed by a a posteriori procedure involving the analytical data. In this work we proposed an approach to geochemical modeling in order to:: i) reconstruct the in-situ reservoir chemical composition (including pH) and ii) evaluate the boundary conditions (e.g. pCO2, pH2S), necessary to implement the reaction path modelling. This is the starting point to assess the geochemical impact of CO2 into the oil reservoir and, as main target, to quantify water-gas-rock reactions. Our geochemical modelling procedure is based on the available data such as: a) bulk mineralogy of the Marly and Vuggy zones; b) average gas-cap composition and c) pre-and post-CO2 injection selected water samples from Midale Beds. The PRHEEQC (V2.11) Software Package was used to reconstruct the in-situ reservoir composition by calculating the chemical equilibrium among the various phases at reservoir temperature (60°C) and pressure (150 bars) conditions by suitable thermodynamic corrections to code database. Then, we identified possible compositions of the initially reservoir liquid phases, always taking into account the case histories of the Marly and Vuggy units. The inverse modelling simulation (IMS) was then performed in order to calculate the amounts of mass transfer of liquid, gas and solid phases that accounted for changes in the water chemistry between the 2000 and 2003 data-sets. IMS calculations suggest that the reservoir underwent mineralogical changes, such as precipitation of chalcedony, gypsum and kaolinite and dissolution of anhydrite and k-feldspar. Calcite dissolution is predicted, but the precipitation of others carbonates (dolomite, dawsonite and siderite) can also occur. Finally, we modelled the geochemical impact of CO2 injection on Weyburn reservoir subjected to both local equilibrium and kinetically controlled reactions. All experimental data and thermo-kinetic modeling of the evolution of the CO2-rich Weyburn brine interacting with host rock minerals performed over 100 years after injection confirm that “solubility trapping” is prevailing in this early stage of CO2 injection. Further and detailed studies on the evolution of the CO2-rich Weyburn brine is one of main aims of this study in the framework of a PhD programme between the INGV of Rome and the Department of Earth Sciences of Florence.
    Description: Published
    Description: Berkeley, California
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Geochemical Modeling CO2 Capture and Storage ; Weyburn Field CO2-EOR ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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